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Liquid crystal networks combine the orientational order of liquid crystals with the elastic properties of polymer networks, leading to a vast application potential in the field of responsive coatings, e.g., for haptic feedback, self-cleaning surfaces and static and dynamic pattern formation. Recent experimental work has further paved the way toward such applications by realizing the fast and reversible surface modulation of a liquid crystal network coating upon in-plane actuation with an AC electric field. Here, we construct a Landau-type theory for electrically-responsive liquid crystal networks and perform Molecular Dynamics simulations to explain the findings of these experiments and inform on rational design strategies. Qualitatively, the theory agrees with our simulations and reproduces the salient experimental features. We also provide a set of testable predictions: the aspect ratio of the nematogens, their initial orientational order when cross-linked into the polymer network and the cross-linking fraction of the network all increase the plasticization time required for the film to macroscopically deform. We demonstrate that the dynamic response to oscillating electric fields is characterized by two resonances, which can likewise be influenced by varying these parameters, providing an experimental handle to fine-tune device design.
Liquid crystal networks exploit the coupling between the responsivity of liquid-crystalline mesogens, e.g., to electric fields, and the (visco)elastic properties of a polymer network. Because of this, these materials have been put forward for a wide
The structure of the half-integer rectilinear disclination line within the framework of the Landau-de Gennes effective theory of nematic liquid crystals is investigated. The consistent perturbative expansion is constructed for the case of $L_2 eq 0$.
In this paper, we study the connection between the Ericksen-Leslie equations and the Beris-Edwards equations in dimension two. It is shown that the weak solutions to the Beris-Edwards equations converge to the one to the Ericksen-Leslie equations as
We propose lyotropic chromonic liquid crystals (LCLCs) as a distinct class of materials for organic electronics. In water, the chromonic molecules stack on top of each other into elongated aggregates that form orientationally ordered phases. The alig
Using computer simulations, we establish that the structure of a supercooled binary atomic liquid mixture consists of common neighbour structures similar to those found in the equilibrium crystal phase, a Laves structure. Despite the large accumulati