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Energy density limitations of layered oxides with different Ni contents, i.e., of the conventional cathode materials in Li-ion batteries, are investigated across the first discharge cycle using advanced spectroscopy and state-of-the-art diffraction. For the first time unambiguous experimental evidence is provided, that redox reactions in NCMs proceed via a reversible oxidation of Ni and a hybridization with O, and not, as widely assumed, via pure cationic or more recently discussed, pure anionic redox processes. Once Ni-O hybrid states are formed, the sites cannot be further oxidized. Instead, irreversible reactions set in which lead to a structural collapse and thus, the lack of ionic Ni limits the reversible capacity. Moreover, the degree of hybridization, which varies with the Ni content, triggers the electronic structure and the operation potential of the cathodes. With an increasing amount of Ni, the covalent character of the materials increases and the potential decreases.
Charged pattern formation on the surfaces of self--assembled cylindrical micelles formed from oppositely charged heterogeneous molecules such as cationic and anionic peptide amphiphiles is investigated. The net incompatibility $chi$ among different c
The reversibility and cyclability of anionic redox in battery electrodes hold the key to its practical employments. Here, through mapping of resonant inelastic X-ray scattering (mRIXS), we have independently quantified the evolving redox states of bo
Fast, reversible redox reactions in solids at low temperatures without thermomechanical degradation are a promising strategy for enhancing the overall performance and lifetime of many energy materials and devices. However, the robust nature of the ca
Electrostatics plays a key role in biomolecular assembly. Oppositely charged biomolecules, for instance, can co-assembled into functional units, such as DNA and histone proteins into nucleosomes and actin-binding protein complexes into cytoskeleton c
We group materials into five symmetry classes and determine in which of these classes phonons carry angular momentum in the Brillouin zone, away from a high-symmetry point, line, or plane. In some materials phonons acquire angular momentum via the fo