ترغب بنشر مسار تعليمي؟ اضغط هنا

CAB: Towards the RNA-world in the interstellar medium -- detection of urea, and search of 2-amino-oxazole and simple sugars

75   0   0.0 ( 0 )
 نشر من قبل Izaskun Jimenez-Serra
 تاريخ النشر 2020
  مجال البحث فيزياء
والبحث باللغة English




اسأل ChatGPT حول البحث

In the past decade, Astrochemistry has witnessed an impressive increase in the number of detections of complex organic molecules. Some of these species are of prebiotic interest such as glycolaldehyde, the simplest sugar, or amino acetonitrile, a possible precursor of glycine. Recently, we have reported the detection of two new nitrogen-bearing complex organics, glycolonitrile and Z-cyanomethanimine, known to be intermediate species in the formation process of ribonucleotides within theories of a primordial ribonucleic acid (RNA)-world for the origin of life. In this paper, we present deep and high-sensitivity observations toward two of the most chemically rich sources in the Galaxy: a Giant Molecular Cloud in the center of the Milky Way (G+0.693-0.027) and a proto-Sun (IRAS16293-2422 B). Our aim is to explore whether the key precursors considered to drive the primordial RNA-world chemistry, are also found in space. Our high-sensitivity observations reveal that urea is present in G+0.693-0.027 with an abundance of about 5x10-11. This is the first detection of this prebiotic species outside a star-forming region. Urea remains undetected toward the proto-Sun IRAS16293-2422 B (upper limit to its abundance of less than 2x10-11). Other precursors of the RNA-world chemical scheme such as glycolaldehyde or cyanamide are abundant in space, but key prebiotic species such as 2- amino-oxazole, glyceraldehyde or dihydroxyacetone are not detected in either source. Future more sensitive observations targeting the brightest transitions of these species will be needed to disentangle whether these large prebiotic organics are certainly present in space.

قيم البحث

اقرأ أيضاً

Some very large (>0.1 um) presolar grains are sampled in meteorites. We reconsider the lifetime of very large grains (VLGs) in the interstellar medium focusing on interstellar shattering caused by turbulence-induced large velocity dispersions. This p ath has never been noted as a dominant mechanism of destruction. We show that, if interstellar shattering is the main mechanism of destruction of VLGs, their lifetime is estimated to be $gtrsim 10^8$ yr; in particular, very large SiC grains can survive cosmic-ray exposure time. However, most presolar SiC grains show residence times significantly shorter than 1 Gyr, which may indicate that there is a more efficient mechanism than shattering in destroying VLGs, or that VLGs have larger velocity dispersions than 10 km s$^{-1}$. We also argue that the enhanced lifetime of SiC relative to graphite can be the reason why we find SiC among $mu$m-sized presolar grains, while the abundance of SiC in the normal interstellar grains is much lower than graphite.
Turbulence is ubiquitous in the insterstellar medium and plays a major role in several processes such as the formation of dense structures and stars, the stability of molecular clouds, the amplification of magnetic fields, and the re-acceleration and diffusion of cosmic rays. Despite its importance, interstellar turbulence, alike turbulence in general, is far from being fully understood. In this review we present the basics of turbulence physics, focusing on the statistics of its structure and energy cascade. We explore the physics of compressible and incompressible turbulent flows, as well as magnetized cases. The most relevant observational techniques that provide quantitative insights of interstellar turbulence are also presented. We also discuss the main difficulties in developing a three-dimensional view of interstellar turbulence from these observations. Finally, we briefly present what could be the the main sources of turbulence in the interstellar medium.
The Interstellar Medium (ISM) comprises gases at different temperatures and densities, including ionized, atomic, molecular species, and dust particles. The neutral ISM is dominated by neutral hydrogen and has ionization fractions up to 8%. The conce ntration of chemical elements heavier than helium (metallicity) spans orders of magnitudes in Galactic stars, because they formed at different times. Instead, the gas in the Solar vicinity is assumed to be well mixed and have Solar metallicity in traditional chemical evolution models. The ISM chemical abundances can be accurately measured with UV absorption-line spectroscopy. However, the effects of dust depletion, which removes part of the metals from the observable gaseous phase and incorporates it into solid grains, have prevented, until recently, a deeper investigation of the ISM metallicity. Here we report the dust-corrected metallicity of the neutral ISM measured towards 25 stars in our Galaxy. We find large variations in metallicity over a factor of 10 (with an average 55 +/- 7% Solar and standard deviation 0.28 dex) and including many regions of low metallicity, down to ~17% Solar and possibly below. Pristine gas falling onto the disk in the form of high-velocity clouds can cause the observed chemical inhomogeneities on scales of tens of pc. Our results suggest that this low-metallicity accreting gas does not efficiently mix into the ISM, which may help us understand metallicity deviations in nearby coeval stars.
In recent years, a plethora of high spectral resolution observations of sub-mm and FIR transitions of methylidene (CH), have demonstrated this radical to be a valuable proxy for H2, that can be used for characterising molecular gas within the interst ellar medium (ISM) on a Galactic scale, including the CO-dark component. Here we report the discovery of the 13CH isotopologue in the ISM using the upGREAT receiver on board SOFIA. We have detected the three hyperfine structure components of the 2THz frequency transition from its ground-state toward four high-mass star-forming regions and determine 13CH column densities. The ubiquity of molecules containing carbon in the ISM has turned the determination of the ratio between the abundances of carbons two stable isotopes, 12C/13C, into a cornerstone for Galactic chemical evolution studies. Whilst displaying a rising gradient with Galactocentric distance, this ratio, when measured using observations of different molecules (CO, H2CO, and others) shows systematic variations depending on the tracer used. These observed inconsistencies may arise from optical depth effects, chemical fractionation or isotope-selective photo-dissociation. Formed from C+ either via UV-driven or turbulence-driven chemistry, CH reflects the fractionation of C+, and does not show any significant fractionation effects unlike other molecules previously used to determine the 12C/13C isotopic ratio which make it an ideal tracer for the 12C/13C ratio throughout the Galaxy. Therefore, by comparing the derived column densities of 13CH with previously obtained SOFIA data of the corresponding transitions of the main isotopologue 12CH, we derive 12C/13C isotopic ratios toward Sgr B2(M), G34.26+0.15, W49(N) and W51E. Adding our values derived from 12/13CH to previous calculations of the Galactic isotopic gradient we derive a revised value of 12C/13C = 5.85(0.50)R_GC + 15.03(3.40).
Deuterium fractionation processes in the interstellar medium (ISM) have been shown to be highly efficient in the family of nitrogen hydrides. To date, observations were limited to ammonia (NH$_2$D, NHD$_2$, ND$_3$) and imidogen radical (ND) isotopolo gues. We want to explore the high frequency windows offered by the emph{Herschel Space Observatory} to search for deuterated forms of amidogen radical NH$_2$ and to compare the observations against the predictions of our comprehensive gas-grain chemical model. Making use of the new molecular spectroscopy data recently obtained at high frequencies for NHD and ND$_2$, both isotopologues have been searched for in the spectral survey towards the class 0 IRAS 16293-2422, a source in which NH$_3$, NH and their deuterated variants have been previously detected. We used the observations carried out with HIFI (Heterodyne Instrument for the Far Infrared) in the framework of the key program Chemical Herschel surveys of star forming regions (CHESS). We report the first detection of interstellar NHD and ND$_2$. Both species are observed in absorption against the continuum of the protostar. From the analysis of their hyperfine structure, accurate excitation temperature and column density values have been determined. The latter were combined with the column density of the parent species NH$_2$ to derive the deuterium fractionation in amidogen. The amidogen D/H ratio measured in the low-mass protostar IRAS 16293-2422 is comparable to the one derived for the related species imidogen and much higher than that observed for ammonia. Additional observations of these species will give more insights into the mechanism of ammonia formation and deuteration in the ISM. We finally indicate the current possibilities to further explore these species at submillimeter wavelengths.
التعليقات
جاري جلب التعليقات جاري جلب التعليقات
سجل دخول لتتمكن من متابعة معايير البحث التي قمت باختيارها
mircosoft-partner

هل ترغب بارسال اشعارات عن اخر التحديثات في شمرا-اكاديميا