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Kinetics parameters for three anion exchange reactions - Zn-LDH-NO3 - Zn-LDH-Cl, Zn-LDH-NO3 - Zn-LDH-SO4 and Zn-LDH-NO3 - Zn-LDH-VOx - were obtained by in situ synchrotron study. The first and the second ones are two-stage reactions; the first stage is characterized by the two-dimensional diffusion-controlled reaction following deceleratory nucleation and the second stage is a one-dimensional diffusion-controlled reaction also with a decelerator nucleation effect. In the case of exchange NO3 - Cl host anions are completely released, while in the case of NO3 - SO42 the reaction ends without complete release of nitrate anions. The exchange of Zn-LDH-NO3 - Zn-LDH-VOx is one-stage reaction and goes much slower than the previous two cases. It is characterized by a one stage two-dimensional reaction and nucleation considered to be instantaneous in this case. As a result, at the end of this process there are two crystalline phases with different polyvanadate species, presumably V4O124 and V2O74, nitrate anions were not completely released. The rate of replacing NO3 anions by guest ones can be represented as Cl > SO42 > VOxy.
The Mg-Zn and Al-Zn binary alloys have been investigated theoretically under static isotropic pressure. The stable phases of these binaries on both initially hexagonal-close-packed (HCP) and face-centered-cubic (FCC) lattices have been determined by
To meet growing energy demands, degradation mechanisms of energy storage devices must be better understood. As a non-destructive tool, X-ray Computed Tomography (CT) has been increasingly used by the battery community to perform $textit{in-situ}$ exp
Amorphous solids, which show characteristic differences from crystals, are common in daily usage. Glasses, gels, and polymers are familiar examples, and polymers are particularly important in terms of their role in construction and crafting. Previous
Lithium-intercalated layered transition-metal oxides, LixTMO2, brought about a paradigm change in rechargeable batteries in recent decades and show promise for use in memristors, a type of device for future neural computing and on-chip storage. Therm
The sub-gap density of states of amorphous indium gallium zinc oxide ($a$-IGZO) is obtained using the ultrabroadband photoconduction (UBPC) response of thin-film transistors (TFTs). Density functional theory simulations classify the origin of the mea