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Experimental and modelling evidence for structural crossover in supercritical CO$_2$

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 نشر من قبل Sarantos Marinakis
 تاريخ النشر 2020
  مجال البحث فيزياء
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Physics of supercritical state is understood to a much lesser degree compared to subcritical liquids. Carbon dioxide in particular has been intensely studied, yet little is known about the supercritical part of its phase diagram. Here, we combine neutron scattering experiments and molecular dynamics simulations and demonstrate the structural crossover at the Frenkel line. The crossover is seen at pressures as high as 14 times the critical pressure and is evidenced by changes of the main features of the structure factor and pair distribution functions.



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