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Time resolved detection of laser induced fluorescence from pulsed excitation of electronic states in barium monofluoride (BaF) molecules has been performed in order to determine the lifetimes of the $A^2Pi_{1/2}$ and $A^2Pi_{3/2}$ states. The method permits control over experimental parameters such that systematic biases in the interpretation of the data can be controlled to below $10^{-3}$ relative accuracy. The statistically limited values for the lifetimes of the $A^2Pi_{1/2}( u=0)$ and $A^2Pi_{3/2}( u=0)$ states are 57.1(3) ns and 47.9(7)~ns, respectively. The ratio of these values is in good agreement with scaling for the different excitation energies. The investigated molecular states are of relevance for an experimental search for a permanent electric dipole moment (EDM) of the electron in BaF.
Magneto-optically trapped atoms enable the determination of lifetimes of metastable states and higher lying excited states like the $rm{5d^{2}~^{3}F_{2}}$ state in barium. The state is efficiently populated by driving strong transitions from metastab
Isotope shifts of the 2$p_{3/2}$-2$p_{1/2}$ transition in B-like ions are evaluated for a wide range of the nuclear charge number: Z=8-92. The calculations of the relativistic nuclear recoil and nuclear size effects are performed using a large scale
The workhorse of atomic physics, quantum electrodynamics, is one of the best-tested theories in physics. However recent discrepancies have shed doubt on its accuracy for complex atomic systems. To facilitate the development of the theory further we a
We report the measurement of the photoionization cross sections of the 5S${}_{1/2}$ and 5P${}_{3/2}$ states of ${}^{87}$Rb in a two-species Hg and Rb magneto-optical trap (MOT) by the cooling laser for Hg. The photoionization cross sections of Rb in
Ab initio calculations of QED radiative corrections to the $^2P_{1/2}$ - $^2P_{3/2}$ fine-structure transition energy are performed for selected F-like ions. These calculations are nonperturbative in $alpha Z$ and include all first-order and many-ele