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Based on first-principles calculations and symmetry-based indicator analysis, we find a class of topological crystalline insulators (TCIs) with $C_2$ rotation anomaly in a family of Zintl compounds, including $mathrm{Ba}_{3}mathrm{Cd}_{2}mathrm{As}_{4}$, $mathrm{Ba}_{3}mathrm{Zn}_{2}mathrm{As}_{4}$ and $mathrm{Ba}_{3}mathrm{Cd}_{2}mathrm{Sb}_{4}$. The nontrivial band topology protected by coexistence of $C_2$ rotation symmetry and time-reversal symmetry $T$ leads to two surface Dirac cones at generic momenta on both top and bottom surfaces perpendicular to the rotation axis. In addition, ($d-2$)-dimensional helical hinge states are also protected along the hinge formed by two side surfaces parallel with the rotation axis. We develop a method based on Wilson loop technique to prove the existence of these surface Dirac cones due to $C_2$ anomaly and precisely locate them as demonstrated in studying these TCIs. The helical hinge states are also calculated. Finally, we show that external strain can be used to tune topological phase transitions among TCIs, strong Z$_2$ topological insulators and trivial insulators.
We show that in the presence of $n$-fold rotation symmetries and time-reversal symmetry, the number of fermion flavors must be a multiple of $2n$ ($n=2,3,4,6$) on two-dimensional lattices, a stronger version of the well-known fermion doubling theorem
Topological crystalline insulators (TCIs) are insulating materials whose topological property relies on generic crystalline symmetries. Based on first-principles calculations, we study a three-dimensional (3D) crystal constructed by stacking two-dime
Topological crystalline insulators (TCIs) are insulating electronic states with nontrivial topology protected by crystalline symmetries. Recently, theory has proposed new classes of TCIs protected by rotation symmetries ^C$_n$, which have surface rot
Two-dimensional higher-order topological insulators can display a number of exotic phenomena such as half-integer charges localized at corners or disclination defects. In this paper, we analyze these phenomena, focusing on the paradigmatic example of
In this work, we identify a new class of Z2 topological insulator protected by non-symmorphic crystalline symmetry, dubbed a topological non-symmorphic crystalline insulator. We construct a concrete tight-binding model with the non-symmorphic space g