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We investigate aluminum abundance variations in the stellar populations of globular clusters using both literature measurements of sodium and aluminum and APOGEE measurements of nitrogen and aluminum abundances. For the latter, we show that the Payne is the most suitable of the five available abundance pipelines for our purposes. Our combined sample of 42 globular clusters spans approximately 2 dex in [Fe/H] and 1.5 dex in $log{M_{GC}/M_{odot}}$. We find no fewer than five globular clusters with significant internal variations in nitrogen and/or sodium with little-to-no corresponding variation in aluminum, and that the minimum present-day cluster mass for aluminum enrichment in metal-rich systems is $log{M_{GC}/M_{odot}} approx 4.50 + 2.17(rm{[Fe/H]}+1.30)$. We demonstrate that the slopes of the [Al/Fe] vs [Na/Fe] and [Al/Fe] vs [N/Fe] relations for stars without field-like abundances are approximately log-linearly dependent on both the metallicity and the stellar mass of the globular clusters. In contrast, the relationship between [Na/Fe] and [N/Fe] shows no evidence of such dependencies. This suggests that there were (at least) two classes of non-supernovae chemical polluters that were common in the early universe, and that their relative contributions within globular clusters somehow scaled with the metallicity and mass of globular clusters. The first of these classes is predominantly responsible for the CNO and NeNa abundance variations, and likewise the second for the MgAl abundance variations. 47 Tuc and M4 are particularly striking examples of this dichotomy. As an auxiliary finding, we argue that abundance variations among Terzan 5 stars are consistent with it being a normal globular cluster.
NGC 6229 is a relatively massive outer halo globular cluster that is primarily known for exhibiting a peculiar bimodal horizontal branch morphology. Given the paucity of spectroscopic data on this cluster, we present a detailed chemical composition a
Although there have been recent claims that there is a large dispersion in the abundances of the heavy neutron capture elements in the old Galactic globular cluster M92, we show that the measured dispersion for the absolute abundances of four of the
Dispersion among the light elements is common in globular clusters (GCs), while dispersion among heavier elements is less common. We present detection of r-process dispersion relative to Fe in 19 red giants of the metal-poor GC M92. Using spectra obt
One of the conundrums in extragalactic astronomy is the discrepancy in observed metallicity distribution functions (MDFs) between the two prime stellar components of early-type galaxies-globular clusters (GCs) and halo field stars. This is generally