ﻻ يوجد ملخص باللغة العربية
High-temperature electrolysis (HTE) is a promising technology for achieving high-efficiency power-to-gas, which mitigates the renewable curtailment by transforming wind or solar energy into fuels. Different from low-temperature electrolysis, a considerable amount of the input energy is consumed by auxiliaries in an HTE system for maintaining the temperature, so the studies on systematic description and parameter optimization of HTE are essentially required. A few published studies investigated HTEs systematic optimization based on simulation, yet there is not a commonly used analytical optimization model which is more suitable for integration with power grid. To fill in this blank, a concise analytical operation model is proposed in this paper to coordinate the necessary power consumptions of auxiliaries under various loading conditions of an HTE system. First, this paper develops a comprehensive energy flow model for an HTE system based on the fundamentals extracted from the existing work, providing a quantitative description of the impacts of condition parameters, including the temperature and the feedstock flow rates. A concise operation model is then analytically proposed to search for the optimal operating states that maximize the hydrogen yield while meeting the desired system loading power by coordinating the temperature, the feedstock flows and the electrolysis current. The evaluation of system performance and the consideration of constraints caused by energy balances and necessary stack requirements are both included. In addition, analytical optimality conditions are obtained to locate the optimal states without performing nonlinear programming by further investigating the optimization method. A numerical case of an HTE system is employed to validate the proposed operation model, which proves to not only improve the conversion efficiency but also enlarge the system load range.
Power-to-gas (P2G) can be employed to balance renewable generation because of its feasibility to operate at fluctuating loading power. The fluctuating operation of low-temperature P2G loads can be achieved by controlling the electrolysis current alon
Hydrogen-rich compounds are extensively explored as candidates for a high-temperature superconductors. Currently, the measured critical temperature of $203$ K in hydrogen sulfide (H$_3$S) is among the highest over all-known superconductors. In presen
Methods of optical dynamic nuclear polarization (DNP) open the door to the replenishable hyperpolarization of nuclear spins, boosting their NMR/MRI signature by orders of magnitude. Nanodiamond powder rich in negatively charged Nitrogen Vacancy (NV)
Hydrogen peroxide (H2O2) formation rates in a proton exchange membrane (PEM) fuel cell anode and cathode were estimated as a function of humidity and temperature by studying the oxygen reduction reaction (ORR) on a rotating ring disc electrode (RRDE)
Many efforts have been dedicated to improve the solar steam generation by using a bi-layer structure. In this paper, a two-dimensional mathematical model describing the water evaporation in a bi-layer structure is firstly established and then the fin