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The L1544 pre-stellar core has been observed as part of the ASAI IRAM 30m Large Program as well as follow-up programs. These observations have revealed the chemical richness of the earliest phases of low-mass star-forming regions. In this paper we focus on the twenty-one sulphur bearing species (ions, isotopomers and deuteration) that have been detected in this spectral-survey through fifty one transitions: CS, CCS, C3S, SO, SO2, H2CS, OCS, HSCN, NS, HCS+, NS+ and H2S. We also report the tentative detection (4 {sigma} level) for methyl mercaptan (CH3SH). LTE and non-LTE radiative transfer modelling have been performed and we used the nautilus chemical code updated with the most recent chemical network for sulphur to explain our observations. From the chemical modelling we expect a strong radial variation for the abundances of these species, which mostly are emitted in the external layer where non thermal desorption of other species has previously been observed. We show that the chemical study cannot be compared to what has been done for the TMC-1 dark cloud, where the abundance is supposed constant along the line of sight, and conclude that a strong sulphur depletion is necessary to fully reproduce our observations of the prototypical pre-stellar core L1544.
Context: The study of dust emission at millimeter wavelengths is important to shed light on the dust properties and physical structure of pre-stellar cores, the initial conditions in the process of star and planet formation. Aims: Using two new conti
Pre-stellar cores represent the initial conditions in the process of star and planet formation, therefore it is important to study their physical and chemical structure. Because of their volatility, nitrogen-bearing molecules are key to study the den
Towards the pre-stellar core L1544, the methanol (CH$_3$OH) emission forms an asymmetric ring around the core centre, where CH$_3$OH is mostly in solid form, with a clear peak 4000~au to the north-east of the dust continuum peak. As part of the NOEMA
The detection of complex organic molecules (COMs) toward cold sources such as pre-stellar cores (with T<10 K), has challenged our understanding of the formation processes of COMs in the interstellar medium. Recent modelling on COM chemistry at low te
We have carried out observations of CCH ($N=1-0$), CH$_{3}$CN ($J=5-4$), and three $^{13}$C isotopologues of HC$_{3}$N ($J=10-9$) toward three massive young stellar objects (MYSOs), G12.89+0.49, G16.86--2.16, and G28.28--0.36, with the Nobeyama 45-m