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When two sessile drops of the same liquid touch, they merge into one drop, driven by capillarity. However, the coalescence can be delayed, or even completely stalled for a substantial period of time, when the two drops have different surface tensions, despite being perfectly miscible. A temporary state of non-coalescence arises, during which the drops move on their substrate, only connected by a thin neck between them. Existing literature covers pure liquids and mixtures with low surface activities. In this paper, we focus on the case of large surface activities, using aqueous surfactant solutions with varying concentrations. It is shown that the coalescence behavior can be classified into three regimes that occur for different surface tensions and contact angles of the droplets at initial contact. However, not all phenomenology can be predicted from surface tension contrast or contact angles alone, but strongly depends on the surfactant concentrations as well. This reveals that the merging process is not solely governed by hydrodynamics and geometry, but also depends on the molecular physics of surface adsorption.
The internal dynamics during the coalescence of a sessile droplet and a subsequently deposited impacting droplet, with either identical or distinct surface tension, is studied experimentally in the regime where surface tension is dominant. Two color
The present article experimentally and theoretically probes the evaporation kinetics of sessile saline droplets. Observations reveal that presence of solvated ions leads to modulated evaporation kinetics, which is further a function of surface wettab
This letter presents a scaling theory of the coalescence of two viscous spherical droplets. An initial value problem was formulated and analytically solved for the evolution of the radius of a liquid neck formed upon droplet coalescence. Two asymptot
We numerically investigate both single and multiple droplet dissolution with droplets consisting of lighter liquid dissolving in a denser host liquid. The significance of buoyancy is quantified by the Rayleigh number Ra which is the buoyancy force ov
This study employs an improved volume of fluid method and adaptive mesh refinement algorithm to numerically investigate the internal jet-like mixing upon the coalescence of two initially stationary droplets of unequal sizes. The emergence of the inte