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تسجيل مستخدم جديدA Co(II)-based Molecular Magnet with a 6 T Coercive Field
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Hard magnets with high coercivity, such as Nd2Fe14B and SmCo5 alloys, can maintain magnetisation under a high reverse external magnetic field and have therefore become irreplaceable parts in many practical applications. Molecular magnets are promising alternatives, owing to their precise and designable chemical structures, tuneable functionalities and controllable synthetic methods. Here, we demonstrate that an unusually large coercive field can be achieved in a single-chain magnet. Systematic characterisations, including magnetic susceptibility, heat capacity and neutron diffraction measurements, show that the observed giant coercive field originates from the spin dynamics along the one-dimensional chain of the compound because of the strong exchange coupling between Co(II) centres and radicals.
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