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A robust potential wherein is embedded the crucial core polarization interaction is used in the Regge Pole methodology to calculate low energy electron elastic scattering total cross section (TCS) for the C60 fullerene in the electron impact energy range 0.02 through 10.0 eV. The energy position of the characteristic dramatically sharp resonance appearing at the second Ramsauer Townsend (RT) minimum of the TCS representing stable C60 fullerene negative ion formation agrees excellently with the measured electron affinity (EA) of C60 [Huang et al 2014 J. Chem. Phys. 140 224315]. The benchmarked potential and the Regge-pole method are then used to calculate electron elastic scattering TCSs for selected fullerenes, from C54 through C240. The TCSs are found to be characterized generally by RT minima, shape resonances (SRs) and dramatically sharp resonances representing long lived ground state fullerene negative ion formation. For the TCSs of C70, C76, C78, and C84 the agreement between the energy positions of the very sharp resonances, corresponding to the binding energies (BEs) of the resultant fullerene negative ions, and the measured EAs is outstanding. Additionally, we extract the BEs of the resultant fullerene negative ions from our calculated TCSs of the C86, C90 and C92 fullerenes with estimated EAs larger than 3.0 eV by the experiment [Boltalina et al, 1993 Rapid Commun. Mass Spectrom. 7 1009] as well as of other fullerenes, including C180 and C240. Most of the TCSs presented in this paper are the first and only. Our novel approach is general and should be applicable to other fullerenes as well and complex heavy atoms, such as the lanthanide atoms. We conclude with a remark on the catalytic properties of the fullerenes through their negative ions.
We provide answers to long-lasting questions in the puzzling behavior of fullerene-fullerene fusion: Why are the fusion barriers so exceptionally high and the fusion cross sections so extremely small? An ab initio nonadiabatic quantum molecular dynam
We analyze using Poisson equation the spatial distributions of the positive charge of carbon atomic nuclei shell and negative charge of electron clouds forming the electrostatic potential of the C60 fullerene shell as a whole. We consider also the ca
A pseudopotential of $C_{60}^-$ has been constructed from ab-initio quantum-mechanical calculations. Since the obtained pseudopotential can be easily fitted by rather simple analytical approximation it can be effectively used both in classical and qu
This is an investigation on the dynamical screening of an atom confined within a fullerene of finite width. The two surfaces of the fullerene lead to the presence of two surface plasmon eigenmodes. It is shown that, in the vicinity of these two eigen
Besides buckminsterfullerene (C60), other fullerenes and their derivatives may also reside in space. In this work, we study the formation and photo-dissociation processes of astronomically relevant fullerene/anthracene (C14H10) cluster cations in the