ترغب بنشر مسار تعليمي؟ اضغط هنا

Large Magnetocaloric effect and magnetic phase transitions in Nd$_2$NiMnO$_6$

105   0   0.0 ( 0 )
 نشر من قبل Yogesh Singh
 تاريخ النشر 2016
  مجال البحث فيزياء
والبحث باللغة English




اسأل ChatGPT حول البحث

We present combined experimental and theoretical investigations on the magnetic and magnetocaloric behavior of Nd$_2$NiMnO$_6$. The relative cooling power (RCP) which quantifies the usefulness of a magnetocaloric (MC) material is estimated to be $approx 300$ J/Kg near the ferromagnetic transition at $T_C approx 195$ K. This RCP is comparable to the best known MC materials. Additionally, the magnetic entropy change has a broad profile ($T_C - 50~{rm K} < T < T_C + 50~{rm K}$) leading to an enhancement in the working-range of temperatures for magnetocaloric based cooling. These features make Nd$_2$NiMnO$_6$ a superior magnetocaloric material compared for example, to the nonmagnetic counterpart Y$_2$NiMnO$_6$. We identify the mechanism for the enhanced RCP which can guide search for future MC materials.



قيم البحث

اقرأ أيضاً

We present a comprehensive experimental study of magnetization and magnetocaloric effect (MCE) in double perovskite (DP) materials $R_2$NiMnO$_6$ with $R =$ Pr, Nd, Sm, Gd, Tb, and Dy. While a paramagnetic to ferromagnetic transition, with T$_{rm C}$ in the range $sim 100 - 200~$K, is a common feature that can be attributed to the ordering of Mn$^{4+}$ and Ni$^{2+}$ magnetic moments, qualitatively distinct behavior depending on the choice of $R$ is observed at low temperatures. These low-temperature anomalies in magnetization are also manifest in the change in magnetic entropy, $-Delta S_{M}$, whose sign depends on the choice of $R$. In order to understand these results, we present theoretical analysis based on mean-field approximation and Monte Carlo simulations on a minimal spin model. The model correctly captures the key features of the experimental observations.
We report a large entropy change (DeltaS) below 300 K, peaking near TC= 220 K, due to isothermal change of magnetic field, for Gd4Co3, with a refrigeration capacity higher than that of Gd. Notably, the isothermal magnetization is nonhysteretic - an i mportant criterion for magnetic refrigeration without loss. DeltaS behavior is also compared with that of magnetoresistance.
93 - L. Shen , M. Laver , E. M. Forgan 2017
We have explored the magnetism in the non-geometrically frustrated spin-chain system $gamma$-CoV$_{2}$O$_{6}$ which possesses a complex magnetic exchange network. Our neutron diffraction patterns at low temperatures ($T$ $leqslant$ $T_{mathrm{N}}$ = 6.6 K) are best described by a model in which two magnetic phases coexist in a volume ratio 65(1) : 35(1), with each phase consisting of a single spin modulation. This model fits previous studies and our observations better than the model proposed by Lenertz $et$ $al$ in J. Phys. Chem. C 118, 13981 (2014), which consisted of one phase with two spin modulations. By decreasing the temperature from $T_{mathrm{N}}$, the minority phase of our model undergoes an incommensurate-commensurate lock-in transition at $T^{*}$ = 5.6 K. Based on these results, we propose that phase separation is an alternative approach for degeneracy-lifting in frustrated magnets.
247 - Wenlong Ma , Xitong Xu , Zihe Wang 2021
We report magnetic and electrical properties for single crystals of NdMn$_6$Sn$_6$ and SmMn$_6$Sn$_6$. They crystallize into a structure which has distorted, Mn-based kagome lattices, compared to the pristine kagome lattices in heavy-rare-earth-beari ng RMn$_6$Sn$_6$ compounds. They are hightemperature ferromagnets of which the R moment is parallel with the Mn moment. We observed a large intrinsic anomalous Hall effect (AHE) that is comparable to the ferrimagnetic, heavy-R siblings in a wide range of temperature. We conclude that their intrinsic AHE is stemming from the Mn-based kagome lattice, just as in the heavy RMn$_6$Sn$_6$.
We investigate the temperature dependence of the spin dynamics in the pyrochlore magnet Nd$_2$Zr$_2$O$_7$ by neutron scattering experiments. At low temperature, this material undergoes a transition towards an all in - all out antiferromagnetic phase and the spin dynamics encompass a dispersion-less mode, characterized by a dynamical spin ice structure factor. Unexpectedly, this mode is found to survive above $T_{rm N} approx 300$ mK. Concomitantly, elastic correlations of the spin ice type develop. These are the signatures of a peculiar correlated paramagnetic phase which can be considered as a new example of Coulomb phase. Our observations near $T_{rm N}$ do not reproduce the signatures expected for a Higgs transition, but show reminiscent features of the all in - all out order superimposed on a Coulomb phase.
التعليقات
جاري جلب التعليقات جاري جلب التعليقات
سجل دخول لتتمكن من متابعة معايير البحث التي قمت باختيارها
mircosoft-partner

هل ترغب بارسال اشعارات عن اخر التحديثات في شمرا-اكاديميا