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We measured the intrinsic hysteretic polarization in lossy improper and nanoferroelectric systems where the nonhysteretic polarization and leakage are large and the relaxation takes place over a broader time scale. We used different measurement protocols such as standard single triangular voltage pulse, a pulse train of PUND (Positive Up Negative Down), and an even more complicated pulse train of fourteen voltage pulses and compared the results obtained. We show that a protocol which sends a train of fourteen pulses is more appropriate for extracting relaxed (i.e., time scale independent) and intrinsic remanent polarization for these samples. We also point out that it is possible to select and design an appropriate measurement protocol depending on the magnitude of polarization and leakage of the system.
Transition metal oxides hold great potential for the development of new device paradigms because of the field-tunable functionalities driven by their strong electronic correlations, combined with their earth abundance and environmental friendliness.
Mobile charges and lattice polarization interact in ferroelectric materials because of the Coulomb interaction between the mobile free charges and the fixed lattice dipoles. We have investigated this mutual screening in KTiOPO4, a ferroelectric/super
The successful theoretical prediction and experimental demonstration of hybrid improper ferroelectricity (HIF) provides a new pathway to couple octahedral rotations, ferroelectricity, and magnetism in complex materials. To enable technological applic
It is of great interest to design and make materials in which ferroelectric polarisation is coupled to other order parameters such as lattice, magnetic and electronic instabilities. Such materials will be invaluable in next-generation data storage de
Improper ferroelectrics are described by two order parameters: a primary one, driving a transition to long-range distortive, magnetic or otherwise non-electric order, and the electric polarization, which is induced by the primary order parameter as a