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تسجيل مستخدم جديدEquilibrium Fluid-Crystal Interfacial Free Energy of Bcc-Crystallizing Aqueous Suspensions of Polydisperse Charged Spheres
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The interfacial free energy is a central quantity in crystallization from the meta-stable melt. In suspensions of charged colloidal spheres, nucleation and growth kinetics can be accurately measured from optical experiments. In previous work, from this data effective non-equilibrium values for the interfacial free energy between the emerging bcc-nuclei and the adjacent melt in dependence on the chemical potential difference between melt phase and crystal phase were derived using classical nucleation theory. A strictly linear increase of the interfacial free energy was observed as a function of increased meta-stability. Here, we further analyze this data for five aqueous suspensions of charged spheres and one binary mixture. We utilize a simple extrapolation scheme and interpret our findings in view of Turnbulls empirical rule. Our first estimates for the reduced interfacial free energy, $sigma_{0,bcc}$, between coexisting equilibrium uid and bcc-crystal phases are on the order of a few $k_BT$. Their values are not correlated to any of the electrostatic interaction parameters but rather show a systematic decrease with increasing size polydispersity and a lower value for the mixture as compared to the pure components. At the same time, $sigma_0$ also shows an approximately linear correlation to the entropy of freezing. The equilibrium interfacial free energy of strictly monodisperse charged spheres may therefore be still greater.
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