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The stereochemical properties of the ultracold ground state OH molecule in the presence of electric and magnetic fields are currently of considerable interest. For example, relevant quantities such as molecular alignment and orientation, calculated numerically by using large basis sets, have lately appeared in the literature. In this work, based on our recent exact solution to an effective eight-dimensional matrix Hamiltonian for the molecular ground state, we present analytic expressions for the stereochemical properties of OH. Our results require the solution of algebraic equations only, agree well with the aforementioned fully numerical calculations, provide compact expressions for simple field geometries, allow ready access to relatively unexplored parameter space, and yield straightforwardly higher moments of the molecular axis distribution.
The OH molecule is currently of great interest from the perspective of ultracold chemistry, quantum fluids, precision measurement and quantum computation. Crucial to these applications are the slowing, guiding, confinement and state control of OH, us
We use accurate quantum mechanical calculations to analyze the effects of parallel electric and magnetic fields on collision dynamics of OH(2Pi) molecules. It is demonstrated that spin relaxation in 3He-OH collisions at temperatures below 0.01 K can
Highly accurate variational calculations, based on a few-parameter, physically adequate trial function, are carried out for the hydrogen molecule hh in inclined configuration, where the molecular axis forms an angle $theta$ with respect to the direct
Photodissociation of a molecule produces a spatial distribution of photofragments determined by the molecular structure and the characteristics of the dissociating light. Performing this basic chemical reaction at ultracold temperatures allows its qu
We present an accurate quantum mechanical study of molecule-molecule collisions in the presence of a magnetic field. The work focusses on the analysis of elastic scattering and spin relaxation in collisions of O2(3Sigma_g) molecules at cold (~0.1 K)