ترغب بنشر مسار تعليمي؟ اضغط هنا

Sub-ms dynamics of the instability onset of electrospinning

52   0   0.0 ( 0 )
 نشر من قبل Dario Pisignano
 تاريخ النشر 2015
  مجال البحث فيزياء
والبحث باللغة English
 تأليف Martina Montinaro




اسأل ChatGPT حول البحث

Electrospun polymer jets are imaged for the first time at an ultra-high rate of 10,000 frames per second, investigating the process dynamics, and the instability propagation velocity and displacement in space. The polymer concentration, applied voltage bias and needle-collector distance are systematically varied, and their influence on the instability propagation velocity and on the jet angular fluctuations analyzed. This allows us to unveil the instability formation and cycling behavior, and its exponential growth at the onset, exhibiting radial growth rates of the order of 10^3 s^-1. Allowing the conformation and evolution of polymeric solutions to be studied in depth, high-speed imaging at sub-ms scale shows a significant potential for improving the fundamental knowledge of electrified jets, leading to obtain finely controllable bending and solution stretching in electrospinning, and consequently better designed nanofibers morphologies and structures.

قيم البحث

اقرأ أيضاً

Complementary Neutron Spin Echo and X-ray experiments and Molecular Dynamics simulations have been performed on difluorotetrachloroethane (CFCl2-CFCl2) glassy crystal. Static, single-molecule reorientational dynamics and collective dynamics propertie s are investigated. The orientational disorder is characterized at different temperatures and a change in nature of rotational dynamics is observed. We show that dynamics can be described by some scaling predictions of the Mode Coupling Theory (MCT) and a critical temperature $T_{c}$ is determined. Our results also confirm the strong analogy between molecular liquids and plastic crystals for which $alpha$-relaxation times and non-ergodicity parameters are controlled by the non trivial static correlations as predicted by MCT.
85 - D. H. Liebenberg 2009
An early study of saturated 4He film flow instability is revisited in view of recent theoretical work by Hiromitsu Takeuchi et al. (arXiv:0909.2144v1 [cond-mat.quant-gas] Sept. 2009). I show additional data that suggests a qualitative agreement with this theory and discuss the experimental details.
The classical flexure problem of non-linear incompressible elasticity is revisited assuming that the bending angle suffered by the block is specified instead of the usual applied moment. The general moment-bending angle relationship is then obtained and is shown to be dependent on only one non-dimensional parameter: the product of the aspect ratio of the block and the bending angle. A Maclaurin series expansion in this parameter is then found. The first-order term is proportional to $mu$, the shear modulus of linear elasticity; the second-order term is identically zero, because the moment is an odd function of the angle; and the third-order term is proportional to $mu(4beta -1)$, where $beta$ is the non-linear shear coefficient, involving third-order and fourth-order elasticity constants. It follows that bending experiments provide an alternative way of estimating this coefficient, and the results of one such experiment are presented. In passing, the coefficients of Rivlins expansion in exact non-linear elasticity are connected to those of Landau in weakly (fourth-order) non-linear elasticity.
Polymer glasses have numerous advantageous mechanical properties in comparison to other materials. One of the most useful is the high degree of toughness that can be achieved due to significant yield occurring in the material. Remarkably, the onset o f plasticity in polymeric materials is very poorly quantified, despite its importance as the ultimate limit of purely elastic behavior. Here we report the results of a novel experiment which is extremely sensitive to the onset of yield and discuss its impact on measurement and elastic theory. In particular, we use an elastic instability to locally bend and impart a textit{local} tensile stress in a thin, glassy polystyrene film, and directly measure the resulting residual stress caused by the bending. We show that plastic failure is initiated at extremely low strains, of order $10^{-3}$ for polystyrene. Not only is this critical strain found to be small in comparison to bulk measurement, we show that it is influenced by thin film confinement - leading to an increase in the critical strain for plastic failure as film thickness approaches zero.
In the cellular phenomena of cytoplasmic streaming, molecular motors carrying cargo along a network of microtubules entrain the surrounding fluid. The piconewton forces produced by individual motors are sufficient to deform long microtubules, as are the collective fluid flows generated by many moving motors. Studies of streaming during oocyte development in the fruit fly $D.~melanogaster$ have shown a transition from a spatially-disordered cytoskeleton, supporting flows with only short-ranged correlations, to an ordered state with a cell-spanning vortical flow. To test the hypothesis that this transition is driven by fluid-structure interactions we study a discrete-filament model and a coarse-grained continuum theory for motors moving on a deformable cytoskeleton, both of which are shown to exhibit a $swirling~instability$ to spontaneous large-scale rotational motion, as observed.
التعليقات
جاري جلب التعليقات جاري جلب التعليقات
mircosoft-partner

هل ترغب بارسال اشعارات عن اخر التحديثات في شمرا-اكاديميا