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Raman spectroscopy is a very powerful probe to study the nature of quasi-particle excitations in condensed matter physics. The work presented in this thesis is focused on two different families of novel materials, namely the iron-based superconductors (FeBS), multiferroic oxides and double perovskite. Although the properties of these two systems are quite different, some comparison can still be drawn between them. For instance, in both of these systems magnetism plays a crucial role and intricate coupling between phononic, magnetic and orbital degrees of freedom is crucial to understand their underlying physics responsible for their various exotic physical properties. Understanding the microscopic origin of quasi-particle excitations, such as phonons, magnons, orbitons, plasmons etc., and coupling between them in these complex materials, has been an intense field of research because it is believed that these excitations hold the key for explaining their rich physics. The systems studied in the thesis include (A) FeBS - (i) FeSe0.82 (ii) Ce1-zYzFeAsO1-xFx (z = 0, 0.4; x = 0.1, 0.2) (iii) Ca4Al2O5.7Fe2As2 (iv) Ca(Fe1-xCox)2As2 (x = 0.03, 0.05). (B) Multiferroic oxides - (i) AlFeO3 (ii) TbMnO3 and double perovskite (iii) La2NiMnO6.
Elucidating the nature of the magnetic ground state of iron-based superconductors is of paramount importance in unveiling the mechanism behind their high temperature superconductivity. Until recently, it was thought that superconductivity emerges onl
The atomic models of nanotubes for layered FeSe, LiFeAs, SrFe2As2, and LnFeAsO - the parent phases of so-called 11, 111, 122, and 1111 groups of newly discovered family of iron-based high temperature superconductors are proposed. On example of SrFe2A
Understanding the overall features of magnetic excitation is essential for clarifying the mechanism of Cooper pair formation in iron-based superconductors. In particular, clarifying the relationship between magnetism and superconductivity is a centra
Ba2ScSbO6 (BSS) has been synthesized in polycrystalline form by solid state reaction. Structural characterization of the compound was done through X-ray diffraction (XRD) followed by Riedvelt analysis of the XRD pattern. The crystal structure is cubi
First-principles FLAPW-GGA band structure calculations were employed to examine the structural, electronic properties and the chemical bonding picture for four ZrCuSiAs-like Th-based quaternary pnictide oxides ThCuPO, ThCuAsO, ThAgPO, and ThAgAsO. Th