ﻻ يوجد ملخص باللغة العربية
A scheme is presented that is based on the alloy analogy model and allows to account for thermal lattice vibrations as well as spin fluctuations when calculating response quantities in solids. Various models to deal with spin fluctuations are discussed concerning their impact on the resulting temperature dependent magnetic moment, longitudinal conductivity and Gilbert damping parameter. It is demonstrated that using the Monte Carlo (MC) spin configuration as an input, the alloy analogy model is capable to reproduce results of MC simulations on the average magnetic moment within all spin fluctuation models under discussion. On the other hand, response quantities are much more sensitive to the spin fluctuation model. Separate calculations accounting for either the thermal effect due to lattice vibrations or spin fluctuations show their comparable contributions to the electrical conductivity and Gilbert damping. However, comparison to results accounting for both thermal effects demonstrate violation of Matthiessens rule, showing the non-additive effect of lattice vibrations and spin fluctuations. The results obtained for bcc Fe and fcc Ni are compared with the experimental data, showing rather good agreement for the temperature dependent electrical conductivity and Gilbert damping parameter.
We combine ab initio simulations and Raman scattering measurements to demonstrate explicit anharmonic effects in the temperature dependent dielectric response of a NaCl single crystal. We measure the temperature evolution of its Raman spectrum and co
We have developed a method to accurately and efficiently determine the vibrational free energy as a function of temperature and volume for substitutional alloys from first principles. Taking Ti$_{1-x}$Al$_x$N alloy as a model system, we calculate the
The accuracy of reconstruction of a response function from its Lorentz integral transform is studied in an exactly solvable model. An inversion procedure is elaborated in detail and features of the procedure are studied. Unlike results in the literat
Finite temperature effects have a pronounced impact on the transport properties of solids. In magnetic systems, besides the scattering of conduction electrons by impurities and phonons, an additional scattering source coming from the magnetic degrees
We investigate a recently developed approach [P. L. Silvestrelli, Phys. Rev. Lett. 100, 053002 (2008); J. Phys. Chem. A 113, 5224 (2009)] that uses maximally localized Wannier functions to evaluate the van der Waals contribution to the total energy o