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تسجيل مستخدم جديدRelativistic calculations of the ground state energies and the critical distances for one-electron homonuclear quasi-molecules
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The ground-state energies of one-electron homonuclear quasi-molecules for the nuclear charge number in the range Z=1-100 at the chemical distances R= 2/Z (in a.u.) are calculated. The calculations are performed for both point- and extended-charge nucleus cases using the Dirac-Fock-Sturm approach with the basis functions constructed from the one-center Dirac-Sturm orbitals. The critical distances R_cr, at which the ground-state level reaches the edge of the negative-energy Dirac continuum, are calculated for homonuclear quasi-molecules in the range: Z=85-100. It is found that in case of U_2^{183+} the critical distance R_cr = 38.42 fm for the point-charge nuclei and R_cr = 34.72 fm for extended nuclei.
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