اشترك بالحزمة الذهبية واحصل على وصول غير محدود شمرا أكاديميا
تسجيل مستخدم جديدLimits to catalysis in quantum thermodynamics
123
0
0.0
(
0
)
اسأل ChatGPT حول البحث
ﻻ يوجد ملخص باللغة العربية
Quantum thermodynamics is a research field that aims at fleshing out the ultimate limits of thermodynamic processes in the deep quantum regime. A complete picture of quantum thermodynamics allows for catalysts, i.e., systems facilitating state transformations while remaining essentially intact in their state, very much reminding of catalysts in chemical reactions. In this work, we present a comprehensive analysis of the power and limitation of such thermal catalysis. Specifically, we provide a family of optimal catalysts that can be returned with minimal trace distance error after facilitating a state transformation process. To incorporate the genuine physical role of a catalyst, we identify very significant restrictions on arbitrary state transformations under dimension or mean energy bounds, using methods of convex relaxations. We discuss the implication of these findings on possible thermodynamic state transformations in the quantum regime.
قيم البحث
اقرأ أيضاً
Noncommuting conserved quantities have recently launched a subfield of quantum thermodynamics. In conventional thermodynamics, a system of interest and a bath exchange quantities -- energy, particles, electric charge, etc. -- that are globally conser
ved and are represented by Hermitian operators. These operators were implicitly assumed to commute with each other, until a few years ago. Freeing the operators to fail to commute has enabled many theoretical discoveries -- about reference frames, entropy production, resource-theory models, etc. Little work has bridged these results from abstract theory to experimental reality. This paper provides a methodology for building this bridge systematically: We present an algorithm for constructing Hamiltonians that conserve noncommuting quantities globally while transporting the quantities locally. The Hamiltonians can couple arbitrarily many subsystems together and can be integrable or nonintegrable. Special cases of our construction have appeared in quantum chromodynamics (QCD). Our Hamiltonians may be realized physically with superconducting qudits, with ultracold atoms, with trapped ions, and in QCD.
We present an overview of the reaction coordinate approach to handling strong system-reservoir interactions in quantum thermodynamics. This technique is based on incorporating a collective degree of freedom of the reservoir (the reaction coordinate)
into an enlarged system Hamiltonian (the supersystem), which is then treated explicitly. The remaining residual reservoir degrees of freedom are traced out in the usual perturbative manner. The resulting description accurately accounts for strong system-reservoir coupling and/or non-Markovian effects over a wide range of parameters, including regimes in which there is a substantial generation of system-reservoir correlations. We discuss applications to both discrete stroke and continuously operating heat engines, as well as perspectives for additional developments. In particular, we find narrow regimes where strong coupling is not detrimental to the performance of continuously operating heat engines.
The entropy produced when a system undergoes an infinitesimal quench is directly linked to the work parameter susceptibility, making it sensitive to the existence of a quantum critical point. Its singular behavior at $T=0$, however, disappears as the
temperature is raised, hindering its use as a tool for spotting quantum phase transitions. Notwithstanding the entropy production can be split into classical and quantum components, related with changes in populations and coherences. In this paper we show that these individual contributions continue to exhibit signatures of the quantum phase transition, even at arbitrarily high temperatures. This is a consequence of their intrinsic connection to the derivatives of the energy eigenvalues and eigenbasis. We illustrate our results in two prototypical quantum critical systems, the Landau-Zener and $XY$ models.
The thermodynamics of a quantum system interacting with an environment that can be assimilated to a harmonic oscillator bath has been extensively investigated theoretically. In recent experiments, the system under study however does not interact dire
ctly with the bath, but though a cavity or a transmission line. The influence on the system from the bath is therefore seen through an intermediate system, which modifies the characteristics of this influence. Here we first show that this problem is elegantly solved by a transform, which we call the Vernon transform, mapping influence action kernels on influence action kernels. We also show that the Vernon transform takes a particularly simple form in the Fourier domain, though it then must be interpreted with some care. Second, leveraging results in quantum thermodynamics we show how the Vernon transform can also be used to compute the generating function of energy changes in the environment. We work out the example of a system interacting with two baths of the Caldeira-Leggett type, each of them seen through a cavity.
We develop a general stochastic thermodynamics of RLC electrical networks built on top of a graph-theoretical representation of the dynamics commonly used by engineers. The network is: open, as it contains resistors and current and voltage sources, n
onisothermal as resistors may be at different temperatures, and driven, as circuit elements may be subjected to external parametric driving. The proper description of the heat dissipated in each resistor requires care within the white noise idealization as it depends on the network topology. Our theory provides the basis to design circuits-based thermal machines, as we illustrate by designing a refrigerator using a simple driven circuit. We also derive exact results for the low temperature regime in which the quantum nature of the electrical noise must be taken into account. We do so using a semiclassical approach which can be shown to coincide with a fully quantum treatment of linear circuits for which canonical quantization is possible. We use it to generalize the Landauer-Buttiker formula for energy currents to arbitrary time-dependent driving protocols.
سجل دخول لتتمكن من نشر تعليقات
التعليقات
جاري جلب التعليقات
سجل دخول لتتمكن من متابعة معايير البحث التي قمت باختيارها
