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Chemical models predict that the deuterated fraction (the column density ratio between a molecule containing D and its counterpart containing H) of N2H+, Dfrac(N2H+), is high in massive pre-protostellar cores and rapidly drops of an order of magnitude after the protostar birth, while that of HNC, Dfrac(HNC), remains constant for much longer. We tested these predictions by deriving Dfrac(HNC) in 22 high-mass star forming cores divided in three different evolutionary stages, from high-mass starless core candidates (HMSCs, 8) to high-mass protostellar objects (HMPOs, 7) to Ultracompact HII regions (UCHIIs, 7). For all of them, Dfrac (N2H+) was already determined through IRAM-30m Telescope observations, which confirmed the theoretical rapid decrease of Dfrac(N2H+) after protostar birth (Fontani et al. 2011). Therefore our comparative study is not affected by biases introduced by the source selection. We have found average Dfrac(HNC) of 0.012, 0.009 and 0.008 in HMSCs, HMPOs and UCHIIs, respectively, with no statistically significant differences among the three evolutionary groups. These findings confirm the predictions of the chemical models, and indicate that large values of Dfrac(N2H+) are more suitable than large values of Dfrac(HNC) to identify cores on the verge of forming high-mass stars, likewise what found in the low-mass regime.
The Millimetre Astronomy Legacy Team 90 GHz (MALT90) survey has detected high-mass star-forming clumps with anomalous N$_2$H$^+$/HCO$^+$(1-0) integrated intensity ratios that are either unusually high (N$_2$H$^+$ rich) or unusually low (N$_2$H$^+$ po
We have observed the HN13C J=1-0 and DNC J=1-0 lines toward 18 massive clumps, including infrared dark clouds (IRDCs) and high-mass protostellar objects (HMPOs), by using the Nobeyama Radio Observatory 45 m telescope. We have found that the HN13C emi
Most stars in the Galaxy, including the Sun, were born in high-mass star-forming regions. It is hence important to study the chemical processes in these regions to better understand the chemical heritage of both the Solar System and most stellar syst
We have undertaken a survey of N2H+ and N2D+ towards 31 low-mass starless cores using the IRAM 30m telescope. Our main objective has been to determine the abundance ratio of N2D+ and N2H+ towards the nuclei of these cores and thus to obtain estimates
We have measured the deuterium fractionation (through the column density ratio N(N2D+)/N(N2H+)) and the CO depletion factor (ratio between expected and observed CO abundance) in a sample of 10 high-mass protostellar candidates, in order to understand