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تسجيل مستخدم جديدGiant pressure-induced volume collapse in the pyrite mineral MnS2
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Dramatic volume collapses under pressure are fundamental to geochemistry and of increasing importance to fields as diverse as hydrogen storage and high-temperature superconductivity. In transition metal materials, collapses are usually driven by so-called spin-state transitions, the interplay between the single-ion crystal field and the size of the magnetic moment. Here we show that the classical S=5/2 mineral Hauerite undergoes an unprecedented 22 % collapse driven by a conceptually different magnetic mechanism. Using synchrotron x-ray diffraction we show that cold compression induces the formation of a disordered intermediate. However, using an evolutionary algorithm we predict a new structure with edge-sharing chains. This is confirmed as the thermodynamic groundstate using in situ laser heating. We show that magnetism is globally absent in the new phase, as low-spin quantum S=1/2 moments are quenched by dimerisation. Our results show how the emergence of metal-metal bonding can stabilise giant spin-lattice coupling in Earths minerals.
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The sudden decrease in molar volume exhibited by most lanthanides under high pressure is often attributed to changes in the degree of localization of their 4f-electrons. We give evidence, based on electrical resistivity measurements of dilute Y(Gd) a
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