اشترك بالحزمة الذهبية واحصل على وصول غير محدود شمرا أكاديميا
تسجيل مستخدم جديدNarrow-bandwidth solar upconversion: design principles, efficiency limits, and case studies
32
0
0.0
(
0
)
اسأل ChatGPT حول البحث
ﻻ يوجد ملخص باللغة العربية
We employ a detailed balance approach to model a single-junction solar cell with a realistic narrow-band, non-unity-quantum-yield upconverter. As upconverter bandwidths are increased from 0 to 0.5 eV, maximum cell efficiencies increase from the Shockley-Queisser limit of 30.58% to over 43%. Such efficiency enhancements are calculated for upconverters with near-infrared spectral absorption bands, readily accessible with existing upconverters. While our model shows that current bimolecular and lanthanide-based upconverting materials will improve cell efficiencies by <1%, cell efficiencies can increase by several absolute percent with increased upconverter quantum yield - even without an increased absorption bandwidth. By examining the efficiency limits of a highly realistic solar cell-upconverter system, our model provides a platform for optimizing future solar upconverter designs.
قيم البحث
اقرأ أيضاً
Taking advantages of ultra-narrow bandwidth and high noise rejection performance of the Faraday anomalous dispersion optical filter (FADOF), simultaneously with the coherent amplification of atomic stimulated emission, a stimulated amplified Faraday
anomalous dispersion optical filter (SAFADOF) at cesium 1470 nm is realized. The SAFADOF is able to significantly amplify very weak laser signals and reject noise in order to obtain clean signals in strong background. Experiment results show that, for a weak signal of 50 pW, the gain factor can be larger than 25000 (44 dB) within a bandwidth as narrow as 13 MHz. Having this ability to amplify weak signals with low background contribution, the SAFADOF finds outstanding potential applications in weak signal detections.
The performance of organic solar cells (OSCs) can be greatly improved by incorporating silica-coated gold nanorods (Au@SiO2 NRs) at the interface between the hole transporting layer and the active layer due to the plasmonic effect. The silica shell i
mpedes the aggregation effect of the Au NRs in ethanol solution as well as the server charge recombination on the surface of the Au NRs otherwise they would bring forward serious reduction in open circuit voltage when incorporating the Au NRs at the positions in contact with the active materials. As a result, while the high open circuit voltage being maintained, the optimized plasmonic OSCs possess an increased short circuit current, and correspondingly an elevated power conversion efficiency with the enhancement factor of ~11%. The origin of performance improvement in OSCs with the Au@SiO2 NRs was analyzed systematically using morphological, electrical, optical characterizations along with theoretical simulation. It is found that the broadband enhancement in absorption, which yields the broadband enhancement in exciton generation in the active layer, is the major factor contributing to the increase in the short circuit current density. Simulation results suggest that the excitation of the transverse and longitudinal surface plasmon resonances of individual NRs as well as their mutual coupling can generate strong electric field near the vicinity of the NRs, thereby an improved exciton generation profile in the active layer. The incorporation of Au@SiO2 NRs at the interface between the hole transporting layer and the active layer also improves hole extraction in the OSCs.
While the basic principles and limitations of conventional solar cells are well understood, relatively little attention has gone toward maximizing the potential efficiency of photovoltaic devices based on shift currents. In this work, we outline simp
le design principles for the optimization of shift currents for frequencies near the band gap, derived from the analysis of a general effective model. The use of a novel sum rule allows us to express the band edge shift current in terms of a few model parameters and to show it depends explicitly on wavefunctions via Berry connections in addition to standard band structure. We use our approach to identify two new classes of shift current photovoltaics, ferroelectric polymer films and single-layer orthorhombic monochalcogenides such as GeS. We introduce tight-binding models for these systems, and show that they exhibit the largest shift current responsivities at the band edge reported so far. Moreover, exploring the parameter space of these models we find photoresponsivities that can exceed $100$ mA/W. Our results show how the study of the shift current via effective models allows one to improve the possible efficiency of devices based on this mechanism and better grasp their potential to compete with conventional solar cells.
The quantum well solar cell (QWSC) has been proposed as a flexible means to ensuring current matching for tandem cells. This paper explores the further advantage afforded by the indication that QWSCs operate in the radiative limit because radiative c
ontribution to the dark current is seen to dominate in experimental data at biases corresponding to operation under concentration. The dark currents of QWSCs are analysed in terms of a light and dark current model. The model calculates the spectral response (QE) from field bearing regions and charge neutral layers and from the quantum wells by calculating the confined densities of states and absorption coefficient, and solving transport equations analytically. The total dark current is expressed as the sum of depletion layer and charge neutral radiative and non radiative currents consistent with parameter values extracted from QE fits to data. The depletion layer dark current is a sum of Shockley-Read-Hall non radiative, and radiative contributions. The charge neutral region contribution is expressed in terms of the ideal Shockley radiative and non-radiative currents modified to include surface recombination. This analysis shows that the QWSC is inherently subject to the fundamental radiative efficiency limit at high currents where the radiative dark current dominates, whereas good homojunction cells are well described by the ideal Shockley picture where the limit is determined by radiative and non radiative recombination in the charge neutral layers of the cell.
We propose a two-stage multi-objective optimization framework for full scheme solar cell structure design and characterization, cost minimization and quantum efficiency maximization. We evaluated structures of 15 different cell designs simulated by v
arying material types and photodiode doping strategies. At first, non-dominated sorting genetic algorithm~II (NSGA-II) produced Pareto-optimal-solutions sets for respective cell designs. Then, on investigating quantum efficiencies of all cell designs produced by NSGA-II, we applied a new multi-objective optimization algorithm~II (OptIA-II) to discover the Pareto fronts of select (three) best cell designs. Our designed OptIA-II algorithm improved the quantum efficiencies of all select cell designs and reduced their fabrication costs. We observed that the cell design comprising an optimally doped zinc-oxide-based transparent conductive oxide (TCO) layer and rough silver back reflector (BR) offered a quantum efficiency ($Q_e$) of $0.6031.$ Overall, this paper provides a full characterization of cell structure designs. It derives a relationship between quantum efficiency, $Q_e$ of a cell with its TCO layers doping methods and TCO and BR layers material types. Our solar cells design characterization enables us to perform a cost-benefit analysis of solar cells usage in real-world applications
سجل دخول لتتمكن من نشر تعليقات
التعليقات
جاري جلب التعليقات
سجل دخول لتتمكن من متابعة معايير البحث التي قمت باختيارها
