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Search for quantum electronic dipoles in the dimerized kappa-(BEDT-TTF)2Cu[N(CN)2]Cl salt

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 نشر من قبل Tomislav Ivek
 تاريخ النشر 2012
  مجال البحث فيزياء
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The Mott insulator kappa-(BEDT-TTF)2Cu[N(CN)2]Cl consists of molecular dimers arranged on an anisotropic triangular lattice and develops a canted antiferromagnetic ground state. It has recently been suggested that this system features purely electronic ferroelectricity which requires an electric dipole moment. Optical spectroscopy clearly rules out charge imbalance in this system, which excludes the existence of quantum electric dipoles on the dimers and subsequently a dipolar spin coupling. We suggest that the prominent in-plane dielectric response in kappa-(BEDT-TTF)2Cu[N(CN)2]Cl is due to short-range discommensurations of the antiferromagnetic phase in the temperature range 30 < T < 50 K, and domain wall relaxations at lower temperatures.



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