اشترك بالحزمة الذهبية واحصل على وصول غير محدود شمرا أكاديميا
تسجيل مستخدم جديدNon-magnetic and magnetic thiolate-protected Au25 superatoms on Cu(111), Ag(111) and Au(111) surfaces
155
0
0.0
(
0
)
اسأل ChatGPT حول البحث
ﻻ يوجد ملخص باللغة العربية
Geometry, electronic structure, and magnetic properties of methylthiolate-stabilized Au$_{25}$L$_{18}$ and MnAu$_{24}$L$_{18}$ (L = SCH$_3$) clusters adsorbed on noble-metal (111) surfaces have been investigated by using spin-polarized density functional theory computations. The interaction between the cluster and the surface is found to be mediated by charge transfer mainly from or into the ligand monolayer. The electronic properties of the 13-atom metal core remain in all cases rather undisturbed as compared to the isolated clusters in gas phase. The Au$_{25}$L$_{18}$ cluster retains a clear HOMO - LUMO energy gap in the range of 0.7 eV to 1.0 eV depending on the surface. The ligand layer is able to decouple the electronic structure of the magnetic MnAu$_{24}$L$_{18}$ cluster from Au(111) surface, retaning a high local spin moment of close to 5 $mu_{B}$ arising from the spin-polarized Mn(3d) electrons. These computations imply that the thiolate monolayer-protected gold clusters may be used as promising building blocks with tunable energy gaps, tunneling barriers, and magnetic moments for applications in the area of electron and/or spin transport.
قيم البحث
اقرأ أيضاً
We investigate equilibrium and transport properties of a copper phthalocyanine (CuPc) molecule adsorbed on Au(111) and Ag(111) surfaces. The CuPc molecule has essentially three localized orbitals close to the Fermi energy resulting in strong local Co
ulomb repulsion not accounted for properly in density functional calculations. Hence, they require a proper many-body treatment within, e.g., the Anderson impurity model (AIM). The occupancy of these orbitals varies with the substrate on which CuPc is adsorbed. Starting from density functional theory calculations, we determine the parameters for the AIM embedded in a noninteracting environment that describes the residual orbitals of the entire system. While correlation effects in CuPc on Au(111) are already properly described by a single orbital AIM, for CuPc on Ag(111) the three orbital AIM problem can be simplified into a two orbital problem coupled to the localized spin of the third orbital. This results in a Kondo effect with a mixed character, displaying a symmetry between SU(2) and SU(4). The computed Kondo temperature is in good agreement with experimental values. To solve the impurity problem we use the recently developed fork tensor product state solver. To obtain transport properties, a scanning tunneling microscope (STM) tip is added to the CuPc molecule absorbed on the surface. We find that the transmission depends on the detailed position of the STM tip above the CuPc molecule in good agreement with differential conductance measurements.
We present a detailed theoretical investigation on the magnetic properties of small single-layered Fe, Co and Ni clusters deposited on Ir(111), Pt(111) and Au(111). For this a fully relativistic {em ab-initio} scheme based on density functional theor
y has been used. We analyse the element, size and geometry specific variations of the atomic magnetic moments and their mutual exchange interactions as well as the magnetic anisotropy energy in these systems. Our results show that the atomic spin magnetic moments in the Fe and Co clusters decrease almost linearly with coordination on all three substrates, while the corresponding orbital magnetic moments appear to be much more sensitive to the local atomic environment. The isotropic exchange interaction among the cluster atoms is always very strong for Fe and Co exceeding the values for bulk bcc Fe and hcp Co, whereas the anisotropic Dzyaloshinski-Moriya interaction is in general one or two orders of magnitude smaller when compared to the isotropic one. For the magnetic properties of Ni clusters the magnetic properties can show quite a different behaviour and we find in this case a strong tendency towards noncollinear magnetism.
We have theoretically studied the stability and reconstruction of (111) surfaces of Au, Pt, and Cu. We have calculated the surface energy, surface stress, interatomic force constants, and other relevant quantities by ab initio electronic structure ca
lculations using the density functional theory (DFT), in a slab geometry with periodic boundary conditions. We have estimated the stability towards a quasi-one-dimensional reconstruction by using the calculated quantities as parameters in a one-dimensional Frenkel-Kontorova model. On all surfaces we have found an intrinsic tensile stress. This stress is large enough on Au and Pt surfaces to lead to a reconstruction in which a denser surface layer is formed, in agreement with experiment. The experimentally observed differences between the dense reconstruction pattern on Au(111) and a sparse structure of stripes on Pt(111) are attributed to the details of the interaction potential between the first layer of atoms and the substrate.
We have investigated the magnetism of the bare and graphene-covered (111) surface of a Ni single crystal employing three different magnetic imaging techniques and ab initio calculations, covering length scales from the nanometer regime up to several
millimeters. With low temperature spinpolarized scanning tunneling microscopy (SP-STM) we find domain walls with widths of 60 - 90 nm, which can be moved by small perpendicular magnetic fields. Spin contrast is also achieved on the graphene-covered surface, which means that the electron density in the vacuum above graphene is substantially spin-polarized. In accordance with our ab initio calculations we find an enhanced atomic corrugation with respect to the bare surface, due to the presence of the carbon pz orbitals and as a result of the quenching of Ni surface states. The latter also leads to an inversion of spinpolarization with respect to the pristine surface. Room temperature Kerr microscopy shows a stripe like domain pattern with stripe widths of 3 - 6 {mu}m. Applying in-plane-fields, domain walls start to move at about 13 mT and a single domain state is achieved at 140 mT. Via scanning electron microscopy with polarization analysis (SEMPA) a second type of modulation within the stripes is found and identified as 330 nm wide V-lines. Qualitatively, the observed surface domain pattern originates from bulk domains and their quasi-domain branching is driven by stray field reduction.
Landaus Fermi liquid theory is a cornerstone of quantum many body physics. At its heart is the adiabatic connection between the elementary excitations of an interacting fermion system and those of the same system with the interactions turned off. Rec
ently, this tenet has been challenged with the finding of a non-Landau Fermi liquid, that is a strongly interacting Fermi liquid that cannot be adiabatically connected to a non-interacting system. In particular, a spin-1 two-channel Kondo impurity with single-ion magnetic anisotropy $D$ has a topological quantum phase transition at a critical value $D_c$: for $D < D_c$ the system behaves as an ordinary Fermi liquid with a large Fermi level spectral weight, while above $D_c$ the system is a non-Landau Fermi liquid with a pseudogap at the Fermi level, topologically characterized by a non-trivial Friedel sum rule with non-zero Luttinger integrals. Here, we develop a non-trivial extension of this new Fermi liquid theory to general multi-orbital problems with finite magnetic field and we reinterpret in a unified and consistent fashion several experimental studies of iron phthalocyanine molecules on Au(111) metal substrate that were previously described in disconnected and conflicting ways. The differential conductance measured using a scanning tunneling microscope (STM) shows a zero-bias dip that widens when the molecule is lifted from the surface and is transformed continuously into a peak under an applied magnetic field. Numerically solving a spin-1 impurity model with single-ion anisotropy for realistic parameter values, we robustly reproduce all these central features, allowing us to conclude that iron phthalocyanine molecules on Au(111) constitute the first confirmed experimental realization of a non-Landau Fermi liquid.
سجل دخول لتتمكن من نشر تعليقات
التعليقات
جاري جلب التعليقات
سجل دخول لتتمكن من متابعة معايير البحث التي قمت باختيارها
