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Natural 12CaO$cdot$7Al$_2$O$_3$ (C12A7) is a wide bandgap insulator, but conductivity can be realized by introducing oxygen deficiency. Currently, there are two competing models explaining conductivity in oxygen-deficient C12A7, one involving the electron transfer via a cage conduction band inside the nominal band gap, the other involving electron hopping along framework lattice sites. To help resolve this debate, we probe insulating and conducting C12A7 with X-ray emission, X-ray absorption, and X-ray photoemission spectroscopy, which provide a full picture of both the valence and conduction band edges in these materials. These measurements suggest the existence of a narrow conduction band between the main conduction and valence bands common in both conducting and insulating C12A7 and support the theory that free electrons in oxygen-deficient C12A7 occupy the low-energy states of this narrow band. Our measurements are corroborated with density functional theory calculations.
The electron paramagnetic resonance study for an organic superconductor $beta$-(BEDT-TTF)$_{4}$[(H$_3$O)Ga(C$_2$O$_4$)$_3$]$cdot$C$_6$H$_5$NO$_2$ reveals that superconductivity coexists uniformly with the charge ordered state in one material. In the
The single electron tunneling spectroscopy on superconductor Na$_{x}$CoO$_2$$cdot$ yH$_2$O and its starting compound Na$_{x}$CoO$_2$ has been studied with point-contact method. The spectra of Na$_{x}$CoO$_2$ have two types of distinct shapes at diffe
Neutron Scattering measurements for YBa$_2$Cu$_3$O$_{6.6}$ have identified small magnetic moments that increase in strength as the temperature is reduced below $T^ast$ and further increase below $T_c$. An analysis of the data shows the moments are an
We report on first investigation of the lattice dynamics in the novel superconducting material Na$_{0.35}$CoO$_2$$cdot$1.3H$_2$O and the non-hydrated parent compound Na$_{0.7}$CoO$_2$ by inelastic x-ray scattering. The measured phonon dispersion alon
Polarized and unpolarized neutron triple-axis spectrometry was used to study the dynamical magnetic susceptibility $chi^{primeprime}({bf q},omega)$ as a function of energy ($hbaromega$) and wave vector (${bf q}$) in a wide temperature range for the b