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The disposition of defects in metal oxides is a key attribute exploited for applications from fuel cells and catalysts to superconducting devices and memristors. The most typical defects are mobile excess oxygens and oxygen vacancies, and can be manipulated by a variety of thermal protocols as well as optical and dc electric fields. Here we report the X-ray writing of high-qualitysuperconducting regions, derived from defect ordering, in the superoxygenated layered cuprate, La2CuO4+y. Irradiation of a poor superconductor prepared by rapid thermal quenching results first in growth of ordered regions, with an enhancement of superconductivity becoming visible only after a waiting time, as is characteristic of other systems such as ferroelectrics, where strain must be accommodated for order to become extended. However, in La2CuO4+y, we are able to resolve all aspects of the growth of (oxygen) intercalant order, including an extraordinary excursion from low to high and back to low anisotropy of the ordered regions. We can also clearly associate the onset of high quality superconductivity with defect ordering in two dimensions. Additional experiments with small beams demonstrate a photoresist-free, single-step strategy for writing functional materials.
The unclear relationship between cuprate superconductivity and the pseudogap state remains an impediment to understanding the high transition temperature (Tc) superconducting mechanism. Here we employ magnetic-field-dependent scanning tunneling micro
The cuprate high-temperature superconductors (HTSC) have been the subject of intense study for more than 30 years with no consensus yet on the underlying mechanism of the superconductivity. Conventional wisdom dictates that the mysterious and extraor
We study oxygen K-edge x-ray absorption spectroscopy (XAS) and investigate the validity of the Zhang-Rice singlet (ZRS) picture in overdoped cuprate superconductors. Using large-scale exact diagonalization of the three-orbital Hubbard model, we obser
We report measurements of the phase of the conductivity, $phi_sigmaequiv arg(sigma)$, in the normal state of a $Bi_{2}Sr_{2}CaCu_{2}O_{8+delta}$ (BSCCO) thin film from 0.2-1.0 THz. From $phi_sigma$ we obtain the time delay of the current response, $t
We study optimally doped Bi-2212 ($T_textrm{c}=96$~K) using femtosecond time- and angle-resolved photoelectron spectroscopy. Energy-resolved population lifetimes are extracted and compared with single-particle lifetimes measured by equilibrium photoe