اشترك بالحزمة الذهبية واحصل على وصول غير محدود شمرا أكاديميا
تسجيل مستخدم جديدPhysical property characterization of single step synthesized NdFeAsO0.80F0.20 bulk 50K superconductor
93
0
0.0
(
0
)
اسأل ChatGPT حول البحث
ﻻ يوجد ملخص باللغة العربية
We report an easy single step synthesis route of title compound NdFeAsO0.80F0.20 superconductor having bulk superconductivity below 50 K. The title compound is synthesized via solid-state reaction route by encapsulation in an evacuated (10-3 Torr) quartz tube. Rietveld analysis of powder X-ray diffraction data shows that compound crystallized in tetragonal structure with space group P4/nmm. R(T)H measurements showed superconductivity with Tc (R=0) at 48 K and a very high upper critical field (Hc2) of up to 345 Tesla. Magnetic measurements exhibited bulk superconductivity in terms of diamagnetic onset below 50 K. The lower critical field (Hc1) is around 1000 Oe at 5 K. In normal state i.e., above 60 K, the compound exhibited purely paramagnetic behavior and thus ruling out the presence of any ordered FeOx impurity in the matrix. In specific heat measurements a jump is observed in the vicinity of superconducting transition (Tc) along with an upturn at below T=4 K due to the AFM ordering of Nd+3 ions in the system. The Thermo-electric power (TEP) is negative down to Tc, thus indicating dominant carriers to be of n-type in NdFeAsO0.80F0.20 superconductor. The granularity of the bulk superconducting NdFeAsO0.8F0.2 sample is investigated and the intra and inter grain contributions have been individuated by looking at various amplitude and frequencies of the applied AC drive magnetic field.
قيم البحث
اقرأ أيضاً
We report synthesis, structure/micro-structure, resistivity under magnetic field [R(T)H], Raman spectra, thermoelectric power S(T), thermal conductivity K(T), and magnetization of ambient pressure argon annealed polycrystalline bulk samples of MgB2,
processed under identical conditions. The compound crystallizes in hexagonal structure with space group P6/mmm. Transmission electron microscopy (TEM) reveals electron micrographs showing various types of defect features along with the presence of 3-4nm thick amorphous layers forming the grain boundaries of otherwise crystalline MgB2. Raman spectra of the compound at room temperature exhibited characteristic phonon peak at 600 cm-1. Superconductivity is observed at 37.2K by magnetic susceptibility C(T), resistivity R(T), thermoelectric power S(T), and thermal conductivity K(T) measurements. The power law fitting of R(T) give rise to Debye temperature at 1400K which is found consistent with the theoretical fitting of S(T), exhibiting ThetaD of 1410K and carrier density of 3.81x 1028/m3. Thermal conductivity K(T) shows a jump at 38K, i.e., at Tc, which was missing in some earlier reports. Critical current density (Jc) of up to 105 A/cm2 in 1-2T (Tesla) fields at temperatures (T) of up to 10K is seen from magnetization measurements. The irreversibility field, defined as the field related to merging of M(H) loops is found to be 78, 68 and 42 kOe at 4, 10 and 20K respectively. The superconducting performance parameters viz. irreversibility field (Hirr) and critical current density Jc(H) of the studied MgB2 are improved profoundly with addition of nano-SiC and nano-Diamond. The physical property parameters measured for polycrystalline MgB2 are compared with earlier reports and a consolidated insight of various physical properties is presented.
We report the experimental and theoretical study on magnetic nature of Bi3Ni system. The structure is found to be orthorhombic (Pnma) with lattice parameters a = 8.879{AA} b = 4.0998{AA} and c = 4.099{AA}. The title compound is synthesized via a soli
d state reaction route by quartz vacuum encapsulation of 5N purity stoichiometric ingredients of Ni and Bi. The superconducting transition temperature is found to be 4.1 K as confirmed from magnetization and specific heat measurements. The lower critical field (Hc1) and irreversibility field (Hirr) are around 150 and 3000Oe respectively at 2K. Upper critical field (Hc2) as determined from in field (up to 4 Tesla) ac susceptibility is found to be around 2 Tesla at 2K. The normal state specific heat is fitted using Sommerfeld-Debye equation C(T) = {gamma}T + {beta}T3+{delta}T5 and the parameters obtained are {gamma}= 11.08mJ/mol-K2, {beta}= 3.73mJ/mol-K4 and {delta}= 0.0140mJ/mol-K6. The calculated electronic density of states (DOS) at Fermi level N(EF) and Debye temperature {Theta}D are 4.697 states/eV per formula unit and 127.7K respectively. We also estimated the value of electron phonon coupling constant ({lambda}) to be 1.23, which when substituted in MacMillan equation gives Tc = 4.5K. Density functional (DFT) based calculations for experimentally determined lattice parameters show that Ni in this compound is non-magnetic and ferromagnetic interactions seem to play no role. The Stoner condition I*N(EF) = 0.136 per Ni atom also indicates that system cannot have any ferromagnetism. The fixed spin moment (FSM) calculations by fixing total magnetic moment on the unit cell also suggested that this system does not exhibit any signatures of ferromagnetism.
The single crystal growth and superconducting properties of PbTaSe2 with non-centrosymmetric crystal structure is reported. Using the chemical vapor transport (CVT) technique, PbTaSe2 crystallizes in a layered structure and the crystal symmetry has b
een shown belonging to a non-centrosymmetric space group P6-m2 confirmed by the consistent band picture near the Fermi level between the angle-resolved photoemission spectrum (ARPES) and theoretical calculations. Superconductivity with Tc =3.83 K has been characterized fully with electrical resistivity r{ho}(T), magnetic susceptibility c{hi}(T), and specific heat C(T) measurements using single crystal samples. The superconducting anisotropy, electron-phonon coupling {lambda}ep, superconducting energy gap {Delta}0, and the specific heat jump {Delta}C/{lambda}Tc at Tc confirms that PbTaSe2 can be categorized as a weakly coupled type-II superconductor.
We report synthesis, structure, electrical transport and heat capacity of SmFeAsO. The title compound is synthesized by one-step encapsulation of stoichiometric FeAs, Sm, and Sm2O3 in an evacuated (10-5 Torr) quartz tube by prolong (72 hours) anneali
ng at 1100oC. The as synthesized compound is crystallized in tetragonal structure with P4/nmm space group having lattice parameters a = 3.93726(33) A and c = 8.49802(07) A. The resistance (R-T) measurements on the compound exhibited ground state spin-density-wave (SDW)-like metallic steps below 140 K. Heat capacity CP(T) measurements on the title compound, showed an anomaly at around 140 K, which is reminiscent of the SDW ordering of the compound. At lower temperatures the CP(T) shows a clear peak at around 4.5 K. At lower temperature below 20 K, Cp(T) is also measured under an applied field of 7 Tesla. It is concluded that the CP(T) peak at 4.5 K is due to the anti-ferromagnetic(AFM) ordering of Sm3+ spins. These results are in confirmation with ordering of Sm in Sm2-xCexCuO4.
Solution growth of single crystals of the recently reported new compound Ce2PdIn8 was investigated. When growing from a stoichiometry in a range 2:1:20 - 2:1:35, single crystals of CeIn3 covered by a thin (~50 um) single-crystalline layer of Ce2PdIn8
were mostly obtained. Using palladium richer compositions the thickness of the Ce2PdIn8 layers were increased, which allowed mechanical extraction of single-phase slabs of the desired compound suitable for a thorough study of magnetism and superconductivity. In some solution growth products also CePd3In6 (LaNi3In6 - type of structure) and traces of phases with the stoichiometry CePd2In7, Ce1.5Pd1.5In7 (determined only by EDX) have been identified. Magnetic measurements of the Ce2PdIn8 single crystals reveal paramagnetic behaviour of the Ce3+ ions with significant magnetocrystalline anisotropy. Above 70 K the magnetic susceptibility follows the Curie-Weiss law with considerably different values of the paramagnetic Curie temperature, for the magnetic field applied along the a- (-90 K) and c-(-50 K) axis. Below the reported critical temperature for superconductivity Tc (0.69 K) the electrical resistivity drops to zero. Comparative measurements of the electrical resistivity, heat capacity and AC susceptibility of several crystals reveal that the superconducting transition is strongly sample-dependent.
سجل دخول لتتمكن من نشر تعليقات
التعليقات
جاري جلب التعليقات
سجل دخول لتتمكن من متابعة معايير البحث التي قمت باختيارها
