اشترك بالحزمة الذهبية واحصل على وصول غير محدود شمرا أكاديميا
تسجيل مستخدم جديدCombining electric and magnetic static field for the tuning of the lifetime of zero energy Feshbach resonances: Application to 3He+NH collisions
41
0
0.0
(
0
)
تأليف
T. Stoecklin
اسأل ChatGPT حول البحث
ﻻ يوجد ملخص باللغة العربية
We study the variation of the positions of two magnetically tuned Zero energy Feshbach resonances when a parallel superimposed electric field is applied. We show that their variation as a function of the electric field follows a simple analytical law and is then predictable. We find that depending on the initial state of the diatomic molecule the resonance is either shifted to higher or to lower values of the magnetic field when the electric field is applied. We calculate the Close Coupling lifetimes of these resonances and show that they also follow a simple law as a function of both the magnetic and the electric field. We demonstrate using this expression that the lifetime of the resonances can be maximised by choosing an appropriate value of the applied electric and found a good agreement with the results of our Close Coupling calculations. These results could be checked in future experiments dedicated to the 3He + NH collisions
قيم البحث
اقرأ أيضاً
We present elastic and inelastic spin-changing cross sections for cold and ultracold NH($X,^3Sigma^-$) + NH($X,^3Sigma^-$) collisions, obtained from full quantum scattering calculations on an accurate textit{ab initio} quintet potential-energy surfac
e. Although we consider only collisions in zero field, we focus on the cross sections relevant for magnetic trapping experiments. It is shown that evaporative cooling of both fermionic $^{14}$NH and bosonic $^{15}$NH is likely to be successful for hyperfine states that allow for s-wave collisions. The calculated cross sections are very sensitive to the details of the interaction potential, due to the presence of (quasi-)bound state resonances. The remaining inaccuracy of the textit{ab initio} potential-energy surface therefore gives rise to an uncertainty in the numerical cross-section values. However, based on a sampling of the uncertainty range of the textit{ab initio} calculations, we conclude that the exact potential is likely to be such that the elastic-to-inelastic cross-section ratio is sufficiently large to achieve efficient evaporative cooling. This likelihood is only weakly dependent on the size of the channel basis set used in the scattering calculations.
Elastic and spin-changing inelastic collision cross sections are presented for cold and ultracold magnetically trapped NH. The cross sections are obtained from coupled-channel scattering calculations as a function of energy and magnetic field. We spe
cifically investigate the influence of the intramolecular spin-spin, spin-rotation, and intermolecular magnetic dipole coupling on the collision dynamics. It is shown that $^{15}$NH is a very suitable candidate for evaporative cooling experiments. The dominant trap-loss mechanism in the ultracold regime originates from the intermolecular dipolar coupling term. At higher energies and fields, intramolecular spin-spin coupling becomes increasingly important. Our qualitative results and conclusions are fairly independent of the exact form of the potential and of the size of the channel basis set.
We theoretically study slow collisions of NH$_3$ molecules with He atoms, where we focus in particular on the observation of scattering resonances. We calculate state-to-state integral and differential cross sections for collision energies ranging fr
om 10${}^{-4}$ cm$^{-1}$ to 130 cm$^{-1}$, using fully converged quantum close-coupling calculations. To describe the interaction between the NH${}_3$ molecules and the He atoms, we present a four-dimensional potential energy surface, based on an accurate fit of 4180 {it ab initio} points. Prior to collision, we consider the ammonia molecules to be in their antisymmetric umbrella state with angular momentum $j=1$ and projection $k=1$, which is a suitable state for Stark deceleration. We find pronounced shape and Feshbach resonances, especially for inelastic collisions into the symmetric umbrella state with $j=k=1$. We analyze the observed resonant structures in detail by looking at scattering wavefunctions, phase shifts, and lifetimes. Finally, we discuss the prospects for observing the predicted scattering resonances in future crossed molecular beam experiments with a Stark-decelerated NH$_3$ beam.
We present a detailed analysis of the role of the magnetic dipole-dipole interaction in cold and ultracold collisions. We focus on collisions between magnetically trapped NH molecules, but the theory is general for any two paramagnetic species for wh
ich the electronic spin and its space-fixed projection are (approximately) good quantum numbers. It is shown that dipolar spin relaxation is directly associated with magnetic-dipole induced avoided crossings that occur between different adiabatic potential curves. For a given collision energy and magnetic field strength, the cross-section contributions from different scattering channels depend strongly on whether or not the corresponding avoided crossings are energetically accessible. We find that the crossings become lower in energy as the magnetic field decreases, so that higher partial-wave scattering becomes increasingly important textit{below} a certain magnetic field strength. In addition, we derive analytical cross-section expressions for dipolar spin relaxation based on the Born approximation and distorted-wave Born approximation. The validity regions of these analytical expressions are determined by comparison with the NH + NH cross sections obtained from full coupled-channel calculations. We find that the Born approximation is accurate over a wide range of energies and field strengths, but breaks down at high energies and high magnetic fields. The analytical distorted-wave Born approximation gives more accurate results in the case of s-wave scattering, but shows some significant discrepancies for the higher partial-wave channels. We thus conclude that the Born approximation gives generally more meaningful results than the distorted-wave Born approximation at the collision energies and fields considered in this work.
We discuss the stability of homonuclear and heteronuclear mixtures of 3He and 4He atoms in the metastable 2^3S_1 state (He*) and predict positions and widths of Feshbach resonances by using the Asymptotic Bound-state Model (ABM). All calculations are
performed without fit parameters, using emph{ab-initio} calculations of molecular potentials. One promising very broad Feshbach resonance (Delta B=72.9^{+18.3}_{-19.3} mT) is found that allows for tuning of the inter-isotope scattering length.
سجل دخول لتتمكن من نشر تعليقات
التعليقات
جاري جلب التعليقات
سجل دخول لتتمكن من متابعة معايير البحث التي قمت باختيارها
