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Raman phonons of $alpha$-FeTe and Fe$_{1.03}$Se$_{0.3}$Te$_{0.7}$ single crystals

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 نشر من قبل Qing-Ming Zhang
 تاريخ النشر 2009
  مجال البحث فيزياء
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The polarized Raman scattering spectra of nonsuperconducting $alpha$-FeTe and of the newly discovered, As-free superconductor Fe$_{1.03}$Se$_{0.3}$Te$_{0.7}$ are measured at room temperature on single crystals. The phonon modes are assigned by combining symmetry analysis with first-principles calculations. In the parent compound $alpha$-FeTe, the A$_{1g}$ mode of the Te atom and the B$_{1g}$ mode of the Fe atom are observed clearly, while in superconducting Fe$_{1.03}$Se$_{0.3}$Te$_{0.7}$, only a softened Fe B$_{1g}$ mode can be seen. No electron-phonon coupling feature can be distinguished in the spectra of the two samples. By contrast, the spectra of the superconducting system show a slight enhancement below 300$cm^{-1}$, which may be of electronic origin.

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