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Hyperconjugative Effect on the Electronic Wavefunctions of Ethanol

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 نشر من قبل Shan Tian Xi
 تاريخ النشر 2008
  مجال البحث فيزياء
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Hyperconjugation is a basic conception of chemistry. Its straightforward effect is exhibited by the spatial delocalization characteristics of the electron density distributions or wavefunctions. Such effects on the electron wavefunctions of the highest-occupied molecular orbitals (HOMO) of two ethanol conformers are demonstrated with electron momentum spectroscopy together with natural bond orbital analyses, exhibiting the distinctly different symmetries of the HOMO wavefunctions in momentum space.



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