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A general formalism of X-ray scattering from different kinds of surface morphologies is described. Based on a description of the surface morphology at the atomic scale through the use of the paracrystal model and discrete distributions of distances, the scattered intensity by non-periodic surfaces is calculated over the whole reciprocal space. In one dimension, the scattered intensity by a vicinal surface, the two-level model, the N-level model, the faceted surface and the rough surface are addressed. In two dimensions, the previous results are generalized to the kinked vicinal surface, the two-level vicinal surface and the step meandering on a vicinal surface. The concept of crystal truncation rod is generalized considering also the truncation of a terrace by a step (yielding a terrace truncation rod) and a step by a kink (yielding a step truncation rod).
We studied the resonant diffraction signal from stepped surfaces of SrTiO3 at the Ti 2p -> 3d (L2,3) resonance in comparison with x-ray absorption (XAS) and specular reflectivity data. The steps on the surface form an artificial superstructure suited
The structural investigations of nanomaterials motivated by their large variety and diverse set of applications have attracted considerable attention. In particular, the ever-improving machinery, both in laboratory and at large scale facilities, toge
Surface X-ray scattering studies of electrochemical Stern layer are reported. The Stern layers formed at the interfaces of RuO2 (110) and (100) in 0.1 M CsF electrolyte are compared to the previously reported Stern layer on Pt(111) [Liu et al., J. Ph
Neutron and X-ray scattering represent two state-of-the-art materials characterization techniques that measure materials structural and dynamical properties with high precision. These techniques play critical roles in understanding a wide variety of
The theoretical formulation of x-ray resonant magnetic scattering from rough surfaces and interfaces is given for the diffuse (off-specular) scattering, and general expressions are derived in both the Born approximation (BA) and the distorted-wave Bo