اشترك بالحزمة الذهبية واحصل على وصول غير محدود شمرا أكاديميا
تسجيل مستخدم جديدOn the origin of the $lambda$-transition in liquid Sulphur
66
0
0.0
(
0
)
اسأل ChatGPT حول البحث
ﻻ يوجد ملخص باللغة العربية
Developing a novel experimental technique, we applied photon correlation spectroscopy using infrared radiation in liquid Sulphur around $T_lambda$, i.e. in the temperature range where an abrupt increase in viscosity by four orders of magnitude is observed upon heating within few degrees. This allowed us - overcoming photo-induced and absorption effects at visible wavelengths - to reveal a chain relaxation process with characteristic time in the ms range. These results do rehabilitate the validity of the Maxwell relation in Sulphur from an apparent failure, allowing rationalizing the mechanical and thermodynamic behavior of this system within a viscoelastic scenario.
قيم البحث
اقرأ أيضاً
We show in numerical simulations that a system of two coupled replicas of a binary mixture of hard spheres undergoes a phase transition in equilibrium at a density slightly smaller than the glass transition density for an unreplicated system. This re
sult is in agreement with the theories that predict that such a transition is a precursor of the standard ideal glass transition. The critical properties are compatible with those of an Ising system. The relations of this approach to the conventional approach based on configurational entropy are briefly discussed.
Certain density correlators, measurable via various experimental techniques, are studied in the context of the vulcanization transition. It is shown that these correlators contain essential information about both the vulcanization transition and the
emergent amorphous solid state. Contact is made with various physical ingredients that have featured in experimental studies of amorphous colloidal and gel systems and in theoretical studies of the glassy state.
The observation of non-saturating classical linear magnetoresistivity has been an enigmatic phenomenon in solid state physics. We present a study of a two-dimensional ohmic conductor, including local Hall effect and a self-consistent consideration of
the environment. An equivalent-circuit scheme delivers a simple and convincing argument why the magnetoresistivity is linear in strong magnetic field, provided that current and biasing electric field are misaligned by a nonlocal mechanism. A finite-element model of a two-dimensional conductor is suited to display the situations that create such deviating currents. Besides edge effects next to electrodes, charge carrier density fluctuations are efficiently generating this effect. However, mobility fluctuations that have frequently been related to linear magnetoresistivity are barely relevant. Despite its rare observation, linear magnetoresitivity is rather the rule than the exception in a regime of low charge carrier densities, misaligned current pathways and strong magnetic field.
We view a complex liquid as a network of bonds connecting each particle to its nearest neighbors; the dynamics of this network is a chain of discrete events signaling particles rearrangements. Within this picture, we studied a two-dimensional complex
liquid and found a stretched-exponential decay of the network memory and a power-law for the distribution of the times for which a particle keeps its nearest neighbors; the dependence of this distribution on temperature suggests a possible dynamical critical point. We identified and quantified the underlying spatio-temporal phenomena. The equilibrium liquid represents a hierarchical structure, a mosaic of long-living crystallites partially separated by less-ordered regions. The long-time dynamics of this structure is dominated by particles redistribution between dynamically and structurally different regions. We argue that these are generic features of locally ordered but globally disordered complex systems. In particular, these features must be taken into account by any coarse-grained theory of dynamics of complex fluids and glasses.
We study the behaviour of the inverse participation ratio and the localization transition in infinitely large random matrices through the cavity method. Results are shown for two ensembles of random matrices: Laplacian matrices on sparse random graph
s and fully-connected Levy matrices. We derive a critical line separating localized from extended states in the case of Levy matrices. Comparison between theoretical results and diagonalization of finite random matrices is shown.
سجل دخول لتتمكن من نشر تعليقات
التعليقات
جاري جلب التعليقات
سجل دخول لتتمكن من متابعة معايير البحث التي قمت باختيارها
