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We discuss the detection of 14 rovibrational lines of CH$^+$, obtained with the iSHELL spectrograph on NASAs Infrared Telescope Facility (IRTF) on Maunakea. Our observations in the 3.49 - 4.13 $mu$m spectral region, obtained with a 0.375 slit width that provided a spectral resolving power $lambda/Delta lambda sim 80,000$, have resulted in the unequivocal detection of the $R(0) - R(3)$ and $P(1)-P(10)$ transitions within the $v=1-0$ band of CH$^+$. The $R$-branch transitions are anomalously weak relative to the $P$-branch transitions, a behavior that is explained accurately by rovibronic calculations of the transition dipole moment reported in a companion paper (Changala et al. 2021). Nine infrared transitions of H$_2$ were also detected in these observations, comprising the $S(8)$, $S(9)$, $S(13)$ and $S(15)$ pure rotational lines; the $v=1-0$ $O(4) - O(7)$ lines, and the $v=2-1$ $O(5)$ line. We present a photodissociation region model, constrained by the CH$^+$ and H$_2$ line fluxes that we measured, that includes a detailed treatment of the excitation of CH$^+$ by inelastic collisions, optical pumping, and chemical (formation) pumping. The latter process is found to dominate the excitation of the observed rovibrational lines of CH$^+$, and the model is remarkably successful in explaining both the absolute and relative strengths of the CH$^+$ and H$_2$ lines.
We report the detection of emission in the v=1-0 P(1) (3.51629 micron) and P(2) (3.60776 micron) rovibrational lines of the helium hydride cation (HeH+) from the planetary nebula NGC 7027. These detections were obtained with the iSHELL spectrograph o
We have detected CH$^{+}$ and CH molecular absorption lines from the young compact planetary nebula IC 4997 from high resolution optical spectra. A high-resolution infra-red (H and K bands) spectrum provides detection of H$_2$ emission lines amongst
Optical integral-field spectroscopy was used to investigate the planetary nebula NGC 3242. We analysed the main morphological components of this source, including its knots, but not the halo. In addition to revealing the properties ofthe physical and
We performed detailed chemical abundance analysis of the extremely metal-poor ([Ar/H]-2) halo planetary nebula H4-1 based on the multi-wavelength spectra from Subaru/HDS, GALEX, SDSS, and Spitzer/IRS and determined the abundances of 10 elements. The
Aims. Excitation of far-infrared and submillimetric molecular lines may originate from nonreactive collisions, chemical formation, or far infrared, near-infrared, and optical fluorescences. As a template, we investigate the impact of each of these pr