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تسجيل مستخدم جديدGeneralized Boltzmann distributions for systems strongly coupled to large finite bath -- a microcanonical approach
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The theory of probability shows that, as the fraction $X_n/Yto 0$, the conditional probability for $X_n$, given $X_n+Y in h_{delta}:=[h, h+delta]$, has a limit law $f_{X_n}(x)e^{-psi_n(h_delta)x}$, where $psi_n(h_delta) $ equals to $[partial ln P(Y in y_delta)/partial y]_{y=h}$ plus an additional term, contributed from the correlation between $X_n$ and bath $Y$. By applying this limit law to an isolated composite system consisting of two strongly coupled parts, a system of interest and a large but finite bath, we derive the generalized Boltzmann distribution law for the system of interest in the exponential form of a redefined Hamiltonian and corrected Boltzmann temperature that reflects the modification due to strong system-bath coupling and the large but finite bath.
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