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We experimentally investigate an optical frequency standard based on the 467 nm (642 THz) electric-octupole reference transition 2S1/2(F=0) -> F7/2(F=3) in a single trapped 171Yb+ ion. The extraordinary features of this transition result from the long natural lifetime and from the 4f136s2 configuration of the upper state. The electric quadrupole moment of the 2F7/2 state is measured as -0.041(5) e(a0)^2, where e is the elementary charge and a0 the Bohr radius. We also obtain information on the differential scalar and tensorial components of the static polarizability and of the probe light induced ac Stark shift of the octupole transition. With a real-time extrapolation scheme that eliminates this shift, the unperturbed transition frequency is realized with a fractional uncertainty of 7.1x10^(-17). The frequency is measured as 642 121 496 772 645.15(52) Hz.
Despite being a canonical example of quantum mechanical perturbation theory, as well as one of the earliest observed spectroscopic shifts, the Stark effect contributes the largest source of uncertainty in a modern optical atomic clock through blackbo
Time scales consistently provide precise time stamps and time intervals by combining atomic frequency standards with a reliable local oscillator. Optical frequency standards, however, have not been applied to the generation of time scales, although t
We evaluated the static and dynamic polarizabilities of the 5s^2 ^1S_0 and 5s5p ^3P_0^o states of Sr using the high-precision relativistic configuration interaction + all-order method. Our calculation explains the discrepancy between the recent exper
The ESA mission Space Optical Clock project aims at operating an optical lattice clock on the ISS in approximately 2023. The scientific goals of the mission are to perform tests of fundamental physics, to enable space-assisted relativistic geodesy an
Optical frequency comparison of the 40Ca+ clock transition u_{Ca} (2S1/2-2D5/2, 729nm) against the 87Sr optical lattice clock transition u_{Sr}(1S0-3P0, 698nm) has resulted in a frequency ratio u_{Ca} / u_{Sr} = 0.957 631 202 358 049 9(2 3). The