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To prepare for the unprecedented spatial and spectral resolution provided by ALMA and Herschel/HIFI, chemical models are being benchmarked against each other. It is obvious that chemical models also need well-constrained observations that can serve as references. Photo-dissociation regions (PDRs) are particularly well suited to serve as references because they make the link between diffuse and molecular clouds, thus enabling astronomers to probe a large variety of physical and chemical processes. At a distance of 400 pc (1 corresponding to 0.002 pc), the Horsehead PDR is very close to the prototypical kind of source (i.e. 1D, edge-on) needed to serve as a reference to models.
Deuterium fractionation is known to enhance the [DCO+]/[HCO+] abundance ratio over the D/H elemental ratio of about 1e-5 in the cold and dense gas typically found in pre-stellar cores. We report the first detection and mapping of very bright DCO+ J=3
Recent Herschel and ALMA observations of Photodissociation Regions (PDRs) have revealed the presence of a high thermal pressure (P ~ 10^7-10^8 K cm-3) thin compressed layer at the PDR surface where warm molecular tracer emission (e.g. CH+, SH+, high-
We present the first detection of the l-C3H+ hydrocarbon in the interstellar medium. The Horsehead WHISPER project, a millimeter unbiased line survey at two positions, namely the photo-dissociation region (PDR) and the nearby shielded core, revealed
The ionization fraction plays a key role in the chemistry and dynamics of molecular clouds. We study the H13CO+, DCO+ and HOC+ line emission towards the Horsehead, from the shielded core to the UV irradiated cloud edge, i.e., the Photodissociation Re
After a discussion about the need for observational benchmark for chemical models, we explain 1) why the Horsehead western edge is well suited to serve as reference for models and 2) the steps we are taking toward this goal. We summarize abundances obtained to date and we show recent results.