ﻻ يوجد ملخص باللغة العربية
The rotational spectral lines of c-C$_3$H$_2$ and two kinds of the $^{13}$C isotopic species, c-$^{13}$CCCH$_2$ ($C_{2v}$ symmetry) and c-CC$^{13}$CH$_2$ ($C_s$ symmetry) have been observed in the 1-3 mm band toward the low-mass star-forming region L1527. We have detected 7, 3, and 6 lines of c-C$_3$H$_2$, c-$^{13}$CCCH$_2$ , and c-CC$^{13}$CH$_2$, respectively, with the Nobeyama 45 m telescope, and 34, 6, and 13 lines, respectively, with the IRAM 30 m telescope, where 7, 2, and 2 transitions, respectively, are observed with the both telescopes. With these data, we have evaluated the column densities of the normal and $^{13}$C isotopic species. The [c-C$_3$H$_2$]/[c-$^{13}$CCCH$_2$] ratio is determined to be $310pm80$, while the [c-C$_3$H$_2$]/[c-CC$^{13}$CH$_2$] ratio is determined to be $61pm11$. The [c-C$_3$H$_2$]/[c-$^{13}$CCCH$_2$] and [c-C$_3$H$_2$]/[c-CC$^{13}$CH$_2$] ratios expected from the elemental $^{12}$C/$^{13}$C ratio are 60-70 and 30-35, respectively, where the latter takes into account the statistical factor of 2 for the two equivalent carbon atoms in c-C$_3$H$_2$. Hence, this observation further confirms the dilution of the $^{13}$C species in carbon-chain molecules and their related molecules, which are thought to originate from the dilution of $^{13}$C$^+$ in the gas-phase C$^+$ due to the isotope exchange reaction: $mathrm{^{13}C^++COrightarrow{}^{13}CO+C^+}$. Moreover, the abundances of the two $^{13}$C isotopic species are different from each other. The ratio of c-$mathrm{^{13}CCCH_2}$ species relative to c-$mathrm{CC^{13}CH_2}$ is determined to be $0.20pm0.05$. If $^{13}$C were randomly substituted for the three carbon atoms, the [c-$mathrm{^{13}CCCH_2}$]/[c-$mathrm{CC^{13}CH_2}$] ratio would be 0.5. Hence, the observed ratio indicates that c-$mathrm{CC^{13}CH_2}$ exists more favorably. Possible origins of the different abundances are discussed.
The $^{13}C$ substitutions of molecule $HC_7N$ were observed in TMC-1 using the J = 12 - 11, J = 13 - 12 rotational transitions in the frequency range 12.4 to 13.6 GHz. We present the first detection the $^{13}C$ isotopic species of $HC_7N$ in the in
We derive molecular-gas-phase $^{12}$C/$^{13}$C isotope ratios for the central few 100 pc of the three nearby starburst galaxies NGC 253, NGC 1068, and NGC 4945 making use of the $lambda$ $sim$ 3 mm $^{12}$CN and $^{13}$CN $N$ = 1--0 lines in the ALM
Complex organic molecules with three carbon atoms are found in the earliest stages of star formation. In particular, propenal (C$_2$H$_3$CHO) is a species of interest due to its implication in the formation of more complex species and even biotic mol
Abundances of light elements in dwarf stars of different ages are important constraints for stellar yields, Galactic chemical evolution and exoplanet chemical composition studies. We have measured C and N abundances and $^{12}$C/$^{13}$C ratios for a
We report on the superconducting (SC) properties of Y$_2$C$_3$ with a relatively high transition temperature $T_{rm c}=15.7$ K investigated by $^{13}$C nuclear-magnetic-resonance (NMR) measurements under a magnetic field. The $^{13}$C Knight shift ha