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We report on the superconducting (SC) properties of Y$_2$C$_3$ with a relatively high transition temperature $T_{rm c}=15.7$ K investigated by $^{13}$C nuclear-magnetic-resonance (NMR) measurements under a magnetic field. The $^{13}$C Knight shift has revealed a significant decrease below $T_{rm c}$, suggesting a spin-singlet superconductivity. From an analysis of the temperature dependence of the nuclear spin-lattice relaxation rate $1/T_1$ in the SC state, Y$_2$C$_3$ is demonstrated to be a multigap superconductor that exhibits a large gap $2Delta/k_{rm B}T_{rm c}=5$ at the main band and a small gap $2Delta/k_{rm B}T_{rm c}=2$ at other bands. These results have revealed that Y$_2$C$_3$ is a unique multigap s-wave superconductor similar to MgB$_2$.
A complex structure of the superconducting order parameter in $Ln_2$C$_3$ ($Ln$ = La, Y) is demonstrated by muon spin relaxation ($mu$SR) measurements in their mixed state. The muon depolarization rate [$sigma_{rm v}(T)$] exhibits a characteristic te
We report (13)C NMR characterization of the new superconductor MgCNi_3 (He et al., Nature (411), 54 (2001)). We found that both the uniform spin susceptibility and the spin fluctuations show a strong enhancement with decreasing temperature, and satur
Coupling between $sigma$-bonding electrons and phonons is generally very strong. To metallize $sigma$-electrons provides a promising route to hunt for new high-T$_c$ superconductors. Based on this picture and first-principles density functional calcu
To verify the effect of geometrical frustration, we artificially distort the triangular lattice of quasi-two-dimensional organic conductor $kappa$-(BEDT-TTF)$_2$Cu$_2$(CN)$_3$ [BEDT-TTF: bis(ethylenedithio)terathiofulvalene] by analogous-molecular su
The electron paramagnetic resonance study for an organic superconductor $beta$-(BEDT-TTF)$_{4}$[(H$_3$O)Ga(C$_2$O$_4$)$_3$]$cdot$C$_6$H$_5$NO$_2$ reveals that superconductivity coexists uniformly with the charge ordered state in one material. In the