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We present a method for accurate determination of atomic transition matrix elements at the 10^{-3} level. Measurements of the ac Stark (light) shift around magic-zero wavelengths, where the light shift vanishes, provide precise constraints on the matrix elements. We make the first measurement of the 5s-6p matrix elements in rubidium by measuring the light shift around the 421 nm and 423 nm zeros with a sequence of standing wave pulses. In conjunction with existing theoretical and experimental data, we find 0.3236(9) e a_0 and 0.5230(8) e a_0 for the 5s-6p_{1/2} and 5s-6p_{3/2} elements, respectively, an order of magnitude more accurate than the best theoretical values. This technique can provide needed, accurate matrix elements for many atoms, including those used in atomic clocks, tests of fundamental symmetries, and quantum information.
Motivated by recent interest in their applications, we report a systematic study of Cs atomic properties calculated by a high-precision relativistic all-order method. Excitation energies, reduced matrix elements, transition rates, and lifetimes are d
We report a new measurement of the $n=2$ Lamb shift in Muonium using microwave spectroscopy. Our result of $1047.2(2.3)_textrm{stat}(1.1)_textrm{syst}$ MHz comprises an order of magnitude improvement upon the previous best measurement. This value mat
We define and measure the ratio (R) of the vector ac-Stark effect (or light shift) in the 6S_1/2 and 5D_3/2 states of a single trapped barium ion to 0.2% accuracy at two different off-resonant wavelengths. We earlier found R = -11.494(13) at 514.531n
We experimentally investigate the dynamic instability of Bose-Einstein condensates in an optical ring resonator that is asymmetrically pumped in both directions. We find that, beyond a critical resonator-pump detuning, the system becomes stable regar
We present combined measurements of the spatially-resolved optical spectrum and the total excited-atom number in an ultracold gas of three-level atoms under electromagnetically induced transparency conditions involving high-lying Rydberg states. The