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We define and measure the ratio (R) of the vector ac-Stark effect (or light shift) in the 6S_1/2 and 5D_3/2 states of a single trapped barium ion to 0.2% accuracy at two different off-resonant wavelengths. We earlier found R = -11.494(13) at 514.531nm and now report the value at 1111.68nm, R = +0.4176(8). These observations together yield a value of the <5D||er||4F> matrix element, previously unknown in the literature. Also, comparison of our results with an ab initio calculation of dynamic polarizability would yield a new test of atomic theory and improve the understanding of atomic structure needed to interpret a proposed atomic parity violation experiment.
Using a single trapped barium ion we have developed an rf spectroscopy technique to measure the ratio of the off-resonant vector ac Stark effect (or light shift) in the 6S_{1/2} and 5D_{3/2} states to 0.1% precision. We find R = Delta_S / Delta_D = -
We demonstrate a new method for the direct measurement of atomic dipole transition matrix elements based on techniques developed for quantum information purposes. The scheme consists of measuring dispersive and absorptive off-resonant light-ion inter
We present a method for accurate determination of atomic transition matrix elements at the 10^{-3} level. Measurements of the ac Stark (light) shift around magic-zero wavelengths, where the light shift vanishes, provide precise constraints on the mat
Transition frequencies between low-lying energy levels in a single trapped $^{138}$Ba$^{+}$ ion have been measured with laser spectroscopy referenced to an optical frequency comb. By extracting the frequencies of one-photon and two-photon components
We present a measurement of the branching ratios from the 6P3/2 state of BaII into all dipoleallowed decay channels (6S1/2, 5D3/2 and 5D5/2). Measurements were performed on single 138Ba+ ions in a linear Paul trap with a frequency-doubled mode-locked