Spectral Line Survey toward Young Massive Protostar NGC 2264 CMM3 in the 4 mm, 3 mm, and 0.8 mm Bands

Spectral line survey observations are conducted toward the high-mass protostar candidate NGC 2264 CMM3 in the 4 mm, 3 mm, and 0.8 mm bands with the Nobeyama 45 m telescope and the Atacama Submillimeter Telescope Experiment (ASTE) 10 m telescope. In total, 265 emission lines are detected in the 4 mm and 3 mm bands, and 74 emission lines in the 0.8 mm band. As a result, 36 molecular species and 30 isotopologues are identified. In addition to the fundamental molecular species, many emission lines of carbon-chain molecules such as HC5N, C4H, CCS, and C3S are detected in the 4 mm and 3 mm bands. Deuterated molecular species are also detected with relatively strong intensities. On the other hand, emission lines of complex organic molecules such as HCOOCH3, and CH3OCH3 are found to be weak. For the molecules for which multiple transitions are detected, rotation temperatures are derived to be 7-33 K except for CH3OH. Emission lines with high upper-state energies (Eu > 150 K) are detected for CH3OH, indicating existence of a hot core. In comparison with the chemical composition of the Orion KL, carbon-chain molecules and deuterated molecules are found to be abundant in NGC 2264 CMM3, while sulfur-bearing species and complex organic molecules are deficient. These characteristics indicate chemical youth of NGC 2264 CMM3 in spite of its location at the center of the cluster forming core, NGC 2264 C.

Spectral Line Survey toward Spiral Arm of M51 in the 3 mm and 2 mm Bands

We have conducted a spectral line survey in the 3 mm and 2 mm bands toward two positions in a spiral arm of M51 (NGC 5194) with the IRAM 30 m telescope. In this survey, we have identified 13 molecular species, including CN, CCH, N2H+, HNCO, and CH3OH. Furthermore, 6 isotopologues of the major species have been detected. On the other hand, SiO, HC3N, CH3CN, and the deuterated species such as DCN and DCO+ are not detected. The deuterium fractionation ratios are evaluated to be less than 0.8 % and 1.2 % for DCN/HCN and DCO+/HCO+, respectively. By comparing the results of the two positions with different star formation activities, we have found that the observed chemical compositions do not strongly depend on star formation activities. They seem to reflect a chemical composition averaged over the 1-kpc scale region including many giant molecular clouds. Among the detected molecules CN, CCH, and CH3OH are found to be abundant. High abundances of CN, and CCH are consistent with the above picture of a wide spread distribution of molecules, because they can be produced by photodissociation. On the other hand, it seems likely that CH3OH is liberated into the gas phase by shocks associated with large scale phenomena such as cloud-cloud collisions and/or by non-thermal desorption processes such as photoevaporation due to cosmic-ray induced UV photons. The present result demonstrates a characteristic chemical composition of a giant molecular cloud complex in the spiral arm, which can be used as a standard reference for studying chemistry in AGNs and starbursts.

An Unbiased Spectral Line Survey toward R CrA IRS7B in the 345 GHz Window with ASTE

We have conducted a spectral line survey in the 332 - 364 GHz region with the ASTE 10 m telescope toward R CrA IRS7B, a low-mass protostar in the Class 0 or Class 0/I transitional stage. We have also performed some supplementary observations in the 450 GHz band. In total, 16 molecular species are identified in the 332 - 364 GHz region. Strong emission lines of CN and CCH are observed, whereas complex organic molecules and long carbon-chain molecules which are characteristics of hot corino and warm carbon-chain chemistry (WCCC) source, respectively, are not detected. The rotation temperature of CH3OH is evaluated to be 31 K, which is significantly lower than that reported for the prototypical hot corino IRAS 16293-2422 (~85 K). The deuterium fractionation ratios for CCH and H2CO are obtained to be 0.038 and 0.050, respectively, which are much lower than those in the hot corino. These results suggest a weak hot corino activity in R CrA IRS7B. On the other hand, the carbon-chain related molecules, CCH and c-C3H2, are found to be abundant. However, this source cannot be classified as a WCCC source, since long carbon-chain molecules are not detected. If WCCC and hot corino chemistry represent the two extremes in chemical compositions of low-mass Class 0 sources, R CrA IRS7B would be a source with a mixture of these two chemical characteristics. The UV radiation from the nearby Herbig Ae star R CrA may also affect the chemical composition. The present line survey demonstrates further chemical diversity in low-mass star-forming regions.