Influence of Molecular Solvation on the Conformation of Star Polymers

We have used neutron scattering to investigate the influence of concentration on the conformation of a star polymer. By varying the contrast between the solvent and isotopically labeled stars, we obtain the distributions of polymer and solvent within a star polymer from analysis of scattering data. A correlation between the local desolvation and the inward folding of star branches is discovered. From the perspective of thermodynamics, we find an analogy between the mechanism of polymer localization driven by solvent depletion and that of the hydrophobic collapse of polymers in solutions.

Phase behavior under a non-centrosymmetric interaction: shifted charge colloids investigated by Monte Carlo simulation

Using Monte Carlo simulations, we investigate the structural characteristics of an interacting hard sphere system with shifted charge to elucidate the effect of the non-centrosymmetric interaction on its phase behavior. Two different phase transitions are identified for this model system. Upon increasing the volume fraction, an abrupt liquid-to-crystal transition first occurs at a significantly lower volume fraction in comparison to that of the centro-charged system. This is due to the stronger effective inter-particle repulsion caused by the additional charge anisotropy. Moreover, within the crystal state at higher volume fraction, the system further undergoes a continuous disorder-to-order transition with respect to the charge orientation. Detailed analyses in this work disclose the nature of these transitions, and orientation fluctuation may cause non-centrosymmetric unit cells. The dependence of crystal formation and orientational ordering on temperature was also examined. These findings indicate that the non-centrosymmetric interaction in this work results in additional freedoms to fine-tune the phase diagram and increase the functionalities of materials. Moreover, these model studies are essential to advance our future understanding regarding the fundamental physiochemical properties of novel Janus colloidal particles and protein crystallization conditions.

Dynamical Crossover in Soft Colloids below the Overlap Concentration

The dynamics of soft colloids in solutions is characterized by internal collective motion as well as center-of-mass diffusion. Using neutron scattering we demonstrate that the competition between the relaxation processes associated with these two degrees of freedom results in strong dependence of dynamics and structure on colloid concentration, c, even well below the overlap concentration c*. We show that concurrent with increasing inter-particle collisions, substantial structural dehydration and slowing-down of internal dynamics occur before geometrically defined colloidal overlap develops. While previous experiments have shown that the average size of soft colloids changes very little below c*, we find a marked change in both the internal structure and internal dynamics with concentration. The competition between these two relaxation processes gives rise to a new dynamically-defined dilute threshold concentration well below c*.

Inferring the Inclination of a Black Hole Accretion Disk from Observations of its Polarized Continuum Radiation

Spin parameters of stellar-mass black holes in X-ray binaries are currently being estimated by fitting the X-ray continuum spectra of their accretion disk emission. For this method, it is necessary to know the inclination of the X-ray-producing inner region of the disk. Since the inner disk is expected to be oriented perpendicular to the spin axis of the hole, the usual practice is to assume that the black hole spin is aligned with the orbital angular momentum vector of the binary, and to estimate the inclination of the latter from ellipsoidal modulations in the light curve of the secondary star. We show that the inclination of the disk can be inferred directly if we have both spectral and polarization information on the disk radiation. The predicted degree of polarization varies from 0% to 5% as the disk inclination changes from face-on to edge-on. With current X-ray polarimetric techniques the polarization degree of a typical bright X-ray binary could be measured to an accuracy of 0.1% by observing the source for about 10 days. Such a measurement would constrain the disk inclination to within a degree or two and would significantly improve the reliability of black hole spin estimates. In addition, it would provide new information on the tilt between the black hole spin axis and the orbital rotation axis of the binary, which would constrain any velocity kicks experienced by stellar-mass black holes during their formation.

On Exponential Time Lower Bound of Knapsack under Backtracking

M.Aleknovich et al. have recently proposed a model of algorithms, called BT model, which generalizes both the priority model of Borodin, Nielson and Rackoff, as well as a simple dynamic programming model by Woeginger. BT model can be further divided into three kinds of fixed, adaptive and fully adaptive ones. They have proved exponential time lower bounds of exact and approximation algorithms under adaptive BT model for Knapsack problem. Their exact lower bound is $Omega(2^{0.5n}/sqrt{n})$, in this paper, we slightly improve the exact lower bound to about $Omega(2^{0.69n}/sqrt{n})$, by the same technique, with related parameters optimized.