Different non-equilibrium situations have recently been considered when studying the thermal Casimir--Polder interaction with a body. We show that the Keldysh Green function method provides a very general common framework for such studies where non-e
quilibrium of either the atom or the body with the environment can be accounted for. We apply the results to the case of ground state polar molecules out of equilibrium with their environment, observing several striking effects. We consider thermal Casimir--Polder potentials in planar configurations, and new results for a molecule in a cylindrical cavity are reported, showing similar characteristic behaviour as found in planar geometry.
The controversy concerning the temperature correction to the Casimir force has been ongoing for almost a decade with no view to a solution and has recently been extended to include semiconducting materials. We review some theoretical aspects of forma
l violations of Nernsts heat theorem in the context of Casimir Lifshitz thermodynamics and the role of the exponent of the leading term of the dielectric permittivity with respect to imaginary frequency. A general formalism for calculating the temperature corrections to free energy at low temperatures is developed for systems which do not exhibit such anomalies, and the low temperature behaviour of the free energy in a gap between half-spaces of poorly conducting materials modelled with a Drude type permittivity is calculated.
