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The effect of added salt on the propulsion of Janus platinum-polystyrene colloids in hydrogen peroxide solution is studied experimentally. It is found that micromolar quantities of potassium and silver nitrate salts reduce the swimming velocity by si milar amounts, while leading to significantly different effects on the overall rate of catalytic breakdown of hydrogen peroxide. It is argued that the seemingly paradoxical experimental observations could be theoretically explained by using a generalised reaction scheme that involves charged intermediates and has the topology of two nested loops.
The motion of an artificial micro-scale swimmer that uses a chemical reaction catalyzed on its own surface to achieve autonomous propulsion is fully characterized experimentally. It is shown that at short times, it has a substantial component of dire cted motion, with a velocity that depends on the concentration of fuel molecules. At longer times, the motion reverts to a random walk with a substantially enhanced diffusion coefficient. Our results suggest strategies for designing artificial chemotactic systems.
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