Transport phenomena at the nanoscale are of interest due to the presence of both quantum and classical behavior. In this work, we demonstrate that quantum transport efficiency can be enhanced by a dynamical interplay of the system Hamiltonian with pu
re dephasing induced by a fluctuating environment. This is in contrast to fully coherent hopping that leads to localization in disordered systems, and to highly incoherent transfer that is eventually suppressed by the quantum Zeno effect. We study these phenomena in the Fenna-Matthews-Olson protein complex as a prototype for larger photosynthetic energy transfer systems. We also show that disordered binary tree structures exhibit enhanced transport in the presence of dephasing.
The role of quantum coherence and the environment in the dynamics of excitation energy transfer is not fully understood. In this work, we introduce the concept of dynamical contributions of various physical processes to the energy transfer efficiency
. We develop two complementary approaches, based on a Greens function method and energy transfer susceptibilities, and quantify the importance of the Hamiltonian evolution, phonon-induced decoherence, and spatial relaxation pathways. We investigate the Fenna-Matthews-Olson protein complex, where we find a contribution of coherent dynamics of about 10% and of relaxation of 80%.
Physical implementations of quantum bits can contain coherent transitions to energetically close non-qubit states. In particular, for anharmonic oscillator systems such as the superconducting phase qubit and the transmon a two-level approximation is
insufficient. We apply optimal control theory to the envelope of a resonant Rabi pulse in a qubit in the presence of a single, weakly off-resonant leakage level. The gate error of a spin flip operation reduces by orders of magnitude compared to simple pulse shapes. Near-perfect gates can be achieved for any pulse duration longer than an intrinsic limit given by the nonlinearity. The pulses can be understood as composite sequences that refocus the leakage transition. We also discuss ways to improve the pulse shapes.
