In the perspective of the outstanding developments of high-precision measurements of fundamental constants using polar molecules related to ultimate checks of fundamental theories, we investigate the possibly counterproductive role of black-body radi
ation on a series of diatomic molecules which would be trapped and observed for long durations. We show that the absorption of black-body radiation at room temperature may indeed limit the lifetime of trapped molecules prepared in a well-defined quantum state. Several examples are treated, corresponding to pure rotational absorption, pure vibrational absorption or both. We also investigate the role of a black-body radiation-induced energy shift on molecular levels and how it could affect high-precision frequency measurements.
