The carbon isotope $^{13}$C, in contrast to $^{12}$C, possesses a nuclear magnetic moment and can induce electron spin dephasing in graphene. This effect is usually neglected due to the low abundance of $^{13}$C in natural carbon allotropes ($sim$1 %
). Chemical vapor deposition (CVD) allows for artificial synthesis of graphene solely from a $^{13}$C precursor, potentially amplifying the influence of the nuclear magnetic moments. In this work we study the effect of hyperfine interactions in pure $^{13}$C-graphene on its spin transport properties. Using Hanle precession measurements we determine the spin relaxation time and observe a weak increase of $tau_{s}$ with doping and a weak change of $tau_{s}$ with temperature, as in natural graphene. For comparison we study spin transport in pure $^{12}$C-graphene, also synthesized by CVD, and observe similar spin relaxation properties. As the signatures of hyperfine effects can be better resolved in oblique spin-valve and Hanle configurations, we use finite-element modeling to emulate oblique signals in the presence of a hyperfine magnetic field for typical graphene properties. Unlike in the case of GaAs, hyperfine interactions with $^{13}$C nuclei influence electron spin transport only very weakly, even for a fully polarized nuclear system. Also, in the measurements of the oblique spin-valve and Hanle effects no hyperfine features could be resolved. This work experimentally confirms the weak character of hyperfine interactions and the negligible role of $^{13}$C atoms in the spin dephasing processes in graphene.
Hydrogen adsorbates in graphene are interesting as they are not only strong Coulomb scatterers but they also induce a change in orbital hybridization of the carbon network from sp^2 into sp^3. This change increases the spin-orbit coupling and is expe
cted to largely modify spin relaxation. In this work we report the change in spin transport properties of graphene due to plasma hydrogenation. We observe an up to three-fold increase of spin relaxation time tau_S after moderate hydrogen exposure. This increase of tau_S is accompanied by the decrease of charge and spin diffusion coefficients, resulting in a minor change in spin relaxation length lambda_S. At high carrier density we obtain lambda_S of 7 microns, which allows for spin detection over a distance of 11 microns. After hydrogenation a value of tau_S as high as 2.7 ns is measured at room temperature.
